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1972-28-7

1972-28-7 Structure

1972-28-7 Structure
IdentificationMore
【Name】

Diethyl azodicarboxylate
【CAS】

1972-28-7
【Synonyms】

AZODICARBOXYLIC ACID DIETHYL ESTER
DEAD
DIETHYL AZODICARBOXYLATE
DIETHYL AZODIFORMATE
Diazenedicarboxylic acid, diethyl ester
Diethoxycarbonyldiazene
Diethyl (E)-1,2-diazenedicarboxylate
Diethyl diazodicarboxylate
dlethylazodicarboxylate
Ethyl azodicarboxylate
Formic acid, azodi-, diethyl ester
Dimethyl azodicarboxyate
DIETHYL AZODICARBOXYLATE SOL., 38-40% IN METHYLENE CHLORIDE
DIETHYLAZODICARBOXYLATE 40 WT. % SOLUT&
DIETHYL AZODICARBOXYLATE SOLUTION, ~40% IN TOLUENE
DiethylAzidoCarboxylate
Pure Diethyl azodicarboxylate (40% solution in toluene)
DAD
Diethyl azodicarboxylate, 94%, balance up to 5% dichloromethane
diethyl azodicarboxylate solution
【EINECS(EC#)】

217-821-7
【Molecular Formula】

C6H10N2O4
【MDL Number】

MFCD00009103
【Molecular Weight】

174.15
【MOL File】

1972-28-7.mol
Chemical PropertiesBack Directory
【Appearance】

Clear orange to orange-red liquid
【bp 】

106°C (13 mmHg)
【density 】

1.106
【refractive index 】

n20/D 1.47
【Fp 】

85°C
【storage temp. 】

2-8°C
【Stability:】

Stable, but may explode if heated under confinement. May be shock sensitive. Decomposes vigorously if heated above 100 C. Incompatible with strong acids, strong bases, strong oxidizing agents, strong reducing agents. Light sensitive.
【Sensitive 】

Air Sensitive
【Detection Methods】

NMR,GC
【Detection Methods】

GC,NMR
【BRN 】

908662
【CAS DataBase Reference】

1972-28-7(CAS DataBase Reference)
【NIST Chemistry Reference】

Diethyl azo diformate(1972-28-7)
【Storage Precautions】

Heat sensitive;Store under nitrogen
Safety DataBack Directory
【Hazard Codes 】

F,Xn,Xi
【Risk Statements 】

R5:Heating may cause an explosion.
R11:Highly Flammable.
R20:Harmful by inhalation.
R36/37/38:Irritating to eyes, respiratory system and skin .
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R63:Possible risk of harm to the unborn child.
R65:Harmful: May cause lung damage if swallowed.
R67:Vapors may cause drowsiness and dizziness.
R48/20/22:Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed .
R40:Limited evidence of a carcinogenic effect.
R20/22:Harmful by inhalation and if swallowed .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
【Safety Statements 】

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S47:Keep at temperature not exceeding ... E C (to be specified by the manufacturer) .
S36:Wear suitable protective clothing .
【RIDADR 】

UN 3233 4.1
【WGK Germany 】

3
【F 】

9
【Hazard Note 】

Toxic/Irritant/Flammable
【HazardClass 】

6.1
【PackingGroup 】

III
Raw materials And Preparation ProductsBack Directory
【Raw materials】

DIETHYL HYDRAZODICARBOXYLATE
【Preparation Products】

1-Boc-2-Methylpiperazine-->1,1-Cyclobutanedicarboxylic acid-->5-[(1,3-DIOXO-1,3-DIHYDRO-2H-ISOINDOL-2-YL)METHYL]-2-FURALDEHYDE-->Zidovudine-->BUT-3-YN-1-AMINE-->1-METHYL-PROP-2-YNYLAMINE-->4-((1-METHYLPIPERIDIN-3-YL)METHOXY)-3,5-DICHLOROBENZENAMINE-->2,3-Quinoline dicarboxylic acid -->5-Methylpyridine-2,3-dicarboxylic acid
Material Safety Data Sheet(MSDS)Back Directory
【msds information】

DEAD(1972-28-7).msds
Spectrum DetailBack Directory
【Spectrum Detail】

Diethyl azodicarboxylate(1972-28-7)IR2
Diethyl azodicarboxylate(1972-28-7)13CNMR
Diethyl azodicarboxylate(1972-28-7)IR1
Diethyl azodicarboxylate(1972-28-7)1HNMR
Well-known Reagent Company Product InformationBack Directory
【Alfa Aesar】

Diethyl azodicarboxylate, 97%(1972-28-7)
【Sigma Aldrich】

1972-28-7(sigmaaldrich)
【TCI AMERICA】

Diethyl Azodicarboxylate  (40% in Toluene, ca. 2.2mol/L)(1972-28-7)
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