| Identification | More | 【Name】
Methyl acrylate | 【CAS】
96-33-3 | 【Synonyms】
2-PROPENOIC ACID METHYL ESTER
ACRYLIC ACID METHYL ESTER
AKOS BBS-00004387
MA
METHYL 2-PROPENOATE
METHYL ACRYLATE
METHYL PROPENOATE
[sri773]methylacrylate,monomer
2-Propenoicacidmethylesetr
Acrylate de methyle
acrylatedemethyle
acrylatedemethyle(french)
Acrylsaeuremethylester
CH2=CHCOOCH3
Curithane 103
curithane103
Methacrylate
Methoxycarbonylethylene
Methyl acrylate, inhibited
Methyl ester acrylic acid | 【EINECS(EC#)】
202-500-6 | 【Molecular Formula】
C4H6O2 | 【MDL Number】
MFCD00008627 | 【Molecular Weight】
86.09 | 【MOL File】
96-33-3.mol |
| Chemical Properties | Back Directory | 【Appearance】
colourless liquid | 【mp 】
-75 °C | 【bp 】
80 °C(lit.)
| 【density 】
0.956 g/mL at 25 °C(lit.)
| 【vapor density 】
3 (vs air)
| 【vapor pressure 】
67.5 mm Hg ( 20 °C)
| 【refractive index 】
n20/D 1.402(lit.)
| 【Fp 】
26.6 °F
| 【storage temp. 】
Refrigerator (+4°C) + Flammables area | 【Stability:】
Stable. Incompatible with bases, acids, oxidizing agents, peroxides. May polymerize on exposure to light. Highly flammable. Commercial product may be inhibited by the presence of hydroquinone monomethyl ether. | 【Water Solubility 】
60 g/L (20 ºC) | 【Merck 】
14,6011 | 【BRN 】
605396 | 【CAS DataBase Reference】
96-33-3(CAS DataBase Reference) | 【NIST Chemistry Reference】
2-Propenoic acid, methyl ester(96-33-3) | 【EPA Substance Registry System】
96-33-3(EPA Substance) |
| Safety Data | Back Directory | 【Hazard Codes 】
F,Xn | 【Risk Statements 】
R11:Highly Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R43:May cause sensitization by skin contact. | 【Safety Statements 】
S9:Keep container in a well-ventilated place .
S25:Avoid contact with eyes .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S33:Take precautionary measures against static discharges .
S36/37:Wear suitable protective clothing and gloves .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water) . | 【RIDADR 】
UN 1919 3/PG 2
| 【WGK Germany 】
2
| 【RTECS 】
AT2800000
| 【F 】
8 | 【HazardClass 】
3 | 【PackingGroup 】
II | 【Hazardous Substances Data】
96-33-3(Hazardous Substances Data) |
| Hazard Information | Back Directory | 【General Description】
Colorless volatile liquid with an acrid odor. Flash point 27°F. Vapors may irritate the eyes and respiratory system. Highly toxic by inhalation, ingestion and skin absorption. Less dense than water (0.957 gm / cm3) and slightly soluble in water, hence floats on water. Vapors heavier than air. | 【Reactivity Profile】
METHYL ACRYLATE ignites readily when exposed to heat, flame or sparks. Offers a dangerous fire and explosion hazard. Reacts vigorously with strong oxidizing materials. Forms peroxides when exposed to air that may initiate spontaneous exothermic polymerization. Peroxide formation usually proceeds slowly. Added inhibitor retards polymerization. If the inhibitor is consumed during long storage, explosive polymerization may occur [MCA Case History No. 2033]. Also subject to strongly exothermic polymerization if heated for prolonged periods or contaminated. | 【Air & Water Reactions】
Highly flammable. Forms peroxides when exposed to air that may initiate spontaneous, exothermic polymerization. Peroxide formation usually proceeds slowly. Slightly soluble in water. | 【Health Hazard】
May irritate skin, eyes, respiratory system, and gastro- intestinal tract. Fumes cause tears. |
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