Mercurous oxide,black

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Mercurous oxide,black Basic information
Product Name:Mercurous oxide,black
Synonyms:Mercurous oxide,black;Mercury(Ⅰ)oxide;mercury(Ⅰ)oxidde;MERCURIOUS OXIDE (BLACK);acc.Hahnemann;Mercury(I) oxide;Mercury oxide (Hg2O);Mercurio(I)oxymercury(I)
CAS:15829-53-5
MF:Hg2O
MW:417.1794
EINECS:239-934-0
Product Categories:Inorganics
Mol File:15829-53-5.mol
Mercurous oxide,black Structure
Mercurous oxide,black Chemical Properties
Safety Information
RIDADR 1641
HazardClass 6.1(a)
PackingGroup II
MSDS Information
Mercurous oxide,black Usage And Synthesis
General DescriptionBlack or brownish-black powder. Not a true compound but rather an intimate mixture of metallic mercury and mercuric oxide. Insoluble in water and denser than water (density 9.8 g / cm3). Hence sinks in water.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileMixtures of "Mercurous oxide,black" with barium oxide react vigorously with hydrogen sulfide in air. Explosions may result [Mellor 10:140. 1946-47]. Dissolves in nitric acid. Reacts with hydrochloric acid to give insoluble mercurous chloride (calomel). Contact of the metal oxide caused the explosive decomposition of hydrogen peroxide [Bretherick 5th ed., 1995]. Mixtures with phosphorus or sulfur explode by impact and friction respectively, [Mellor, 1940, Vol. 4, 77].
Health HazardHighly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire HazardNon-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.
Mercurous oxide,black Preparation Products And Raw materials
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Mercurous oxide,black