Company Name: | Zhengzhou Alfachem Co., Ltd. Gold |
Tel: | 0371- 53732842;13383863444 QQ:1065526125 |
Email: | gekun@alfachem.cn |
Products Intro: |
Product Name:Phosphorus oxychloride CAS:10025-87-3 Purity:98% Package:500Ml |
Company Name: | Nanjing Xiezun Chemical Co., Ltd. Gold |
Tel: | 025-85629050 13912997845 |
Email: | tian_zun@126.com |
Products Intro: |
Product Name:Phosphorus oxychloride CAS:10025-87-3 Purity:99% |
Company Name: | Alfa Aesar |
Tel: | 400-610-6006; 021-67582000 |
Email: | saleschina@alfa-asia.com |
Products Intro: |
Product Name:Phosphorus(V) oxychloride, 99.999% (Metals basis) CAS:10025-87-3 Package:5g Remarks:011847 |
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| Phosphorus oxychloride Basic information |
| Phosphorus oxychloride Chemical Properties |
mp | 1.25 °C(lit.)
| bp | 107 °C | density | 1.675 g/mL at 20 °C(lit.)
| vapor density | 5.3 (vs air)
| vapor pressure | 104 mm Hg ( 50 °C)
| refractive index | n20/D 1.461
| Fp | 105.8°C | Water Solubility | reacts exothermically | Sensitive | Moisture Sensitive | Merck | 14,7349 | Stability: | Stable. Reacts violently with water. Incompatible with many metals, alcohols, amines, phenol, DMSO, strong bases. | CAS DataBase Reference | 10025-87-3(CAS DataBase Reference) | NIST Chemistry Reference | Phosphoryl chloride(10025-87-3) | EPA Substance Registry System | Phosphoric trichloride(10025-87-3) |
| Phosphorus oxychloride Usage And Synthesis |
Chemical Properties | colourless liquid | General Description | A colorless fuming liquid with a pungent odor. Density 14.0 lb / gal. Very toxic by inhalation and corrosive to metals and tissue. Used in gasoline additives and hydraulic fluids. | Reactivity Profile | Phosphorus oxychloride is water reactive. Incompatible with strong oxidizing agents, alcohols, bases (including amines). May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Combining the chloride with zinc dust caused immediate ignition, due to the formation of phosphine gas which ignites, [Mellor, 1940, Vol. 8, 1025]. An exotherm starting with the mixing of Phosphorus oxychloride with acetone (a ketone) lead to an explosion, may behave similarly with other ketones, [Organic Process Research and Development, Vol.4, No. 6,200, "Phosphorus oxychloride and Acetone: An Incompatibility Investigation Using ARC."] | Health Hazard | Health Hazards : This poison is toxic by inhalation and ingestion and is strongly irritating to skin and tissues. It causes burns of the mucous membranes of the mouth and digestive tractand may be fatal. | Fire Hazard | Poisonous, corrosive, and irritating gases are generated when Phosphorus oxychloride is heated or is in contact with water. Phosphorus oxychloride may ignite other combustible materials (wood, paper, oil, etc.). Phosphorus oxychloride reacts violently with water. When heated to decomposition, Phosphorus oxychloride emits toxic fumes of chlorides and oxides of phosphorus; Phosphorus oxychloride will react with water or steam to produce heat and toxic and corrosive fumes. Incompatible with carbon disulfide; N,N-dimethylformamide; 2,5-dimethylpyrrole; 2,6-dimethyl- pyridine N-oxide; dimethylsulfoxide; Ferrocene-1,1-dicarboxylic acid; water; and zinc. Do not store with combustible materials, particularly fibrous organic materials, or with electrical or other equipment that can be corroded. Reacts violently with moisture. |
| Phosphorus oxychloride Preparation Products And Raw materials |
Preparation Products | 4-(4-(BIS-(2-CHLOROETHYL)AMINO)BENZYLIDENE-2-PHENYL-OXAZOLINE-5-ONE-->Basic Blue 7-->6-CHLORO-5-CYANO-4-METHOXYMETHYL-3-NITRO-2-PICOLINE-->2-Chloro-3',4'-dihydroxyacetophenone-->DISTARCH PHOSPHATE-->2,6-Dichloro-4,8-dipiperidinopyrimidino[5,4-d]pyrimidine-->4-(Dimethylamino)benzophenone-->4-TRIFLUOROMETHYLBENZYLSULFONYL CHLORIDE-->5-METHYL-2-METHYLSULFANYL-PYRIMIDINE-->2-Chloro-5-thiophenecarboxaldehyde-->CHROMONE-3-CARBOXALDEHYDE-->6-N-HEXYLAMINOPURINE-->2,4-Dichloro-5-nitropyrimidine-->2-CHLORO-4-METHYLQUINOLINE-3-CARBONITRILE-->Quinazoline, 2-methyl- (6CI,7CI,8CI,9CI)-->PYRIDINE-3-SULFONYL CHLORIDE-->2,4,6-Trichloropyridine-->2,2'-BITHIOPHENE-5-CARBOXALDEHYDE-->Thieno[3,2-d]pyrimidine, 2,4-dichloro--->2-Chloro-4-methylpyrimidine-->P-TOLYL-ACETYL CHLORIDE-->2-ETHOXY-1-NAPHTHALDEHYDE-->Tris(2-ethylhexyl) phosphate-->DICAPTHON-->Starch, hydrogen phosphate, 2-hydroxypropyl ether-->Acetylated Dishtarch Phosphate-->Niclosamide-->3-CHLORO-1H-INDAZOLE-->Chloroambucil -->2,4-DICHLOROTHIENO[3,2-D]PYRIMIDINE-->2-Trifluoromethylbenzylsulfonyl chloride-->HEXAFLUOROGLUTARIC ANHYDRIDE-->4-Chloro-7-azaindole-->2-(Chloromethyl)-5-propoxypyridine-->SALICYLIC ACID 4-TERT-BUTYLPHENYL ESTER-->BENZALDEHYDE NITROGEN MUSTARD-->2-CHLOROLEPIDINE-->4,6-Dichloro-5-methoxypyrimidine-->4-Chloro-3,5-dinitrobenzaldehyde-->Disodium 4-nitrophenylphosphate | Raw materials | Chlorine-->Phosphorus trichloride-->Phosphorus pentachloride-->Oxygen-->Sulfur dioxide-->Silicon dioxide-->White phosphorus-->Distillation equipment |
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