Crotonaldehyde

Crotonaldehyde Suppliers list
Company Name:JinYan Chemicals(ShangHai) Co.,Ltd.  
Tel:13817811078,021-50426030
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Products Intro: CAS:123-73-9
Company Name:Shanghai Hanhong Chemical Co., Ltd.  
Tel:021-61521197,021-60496702,021-54302127,021-54306202,021-61525701,021-54308259
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Products Intro: Product Name:CROTONALDEHYDE
CAS:123-73-9
Remarks:RB01040013
Company Name:Chengdu XiYa Chemical Technology Co., Ltd.  
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Products Intro: Product Name:(E)-2-Butenal
CAS:123-73-9
Purity:99% HPLC Package:25g,100g,500g
Company Name:Syntechem Co.,Ltd  
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Products Intro: Product Name:(E)-but-2-enal
CAS:123-73-9
Purity:97% Package:1g;5g;25g;100g;250g;1kg;5kg;10kg;25kg Remarks:we offer low price custom synthesis and contract manufacturing
Company Name:BEST-REAGENT  
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Products Intro: Product Name:(E)-2-Butenal
CAS:123-73-9
Purity:99% Package:5g,25g,100,500g,1Kg
Crotonaldehyde Basic information
Product Name:Crotonaldehyde
Synonyms:BUTENAL;BETA-METHYLACROLEIN;CROTONALDEHYDE;CROTINALDEHYDE;(E)-2-BUTENAL;2-BUTENAL;2-BUTEN-1-AL;TRANS-2-BUTENAL
CAS:123-73-9
MF:C4H6O
MW:70.09
EINECS:204-647-1
Product Categories:Pharmaceutical Intermediates;Aldehydes;C1 to C6;Carbonyl Compounds;Building Blocks;C1 to C6;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
Mol File:123-73-9.mol
Crotonaldehyde Structure
Crotonaldehyde Chemical Properties
mp −76 °C(lit.)
bp 104 °C(lit.)
density 0.853 g/mL at 20 °C(lit.)
vapor density 2.41 (vs air)
vapor pressure 32 mm Hg ( 20 °C)
refractive index n20/D 1.437
Fp 48 °F
storage temp. 2-8°C
Water Solubility 150 g/L (20 ºC)
Merck 14,2596
BRN 906731
CAS DataBase Reference123-73-9(CAS DataBase Reference)
NIST Chemistry ReferenceCrotonaldehyde(123-73-9)
EPA Substance Registry System2-Butenal, (2E)-(123-73-9)
Safety Information
Hazard Codes F,T+,N
Risk Statements 11-24/25-26-37/38-41-48/22-50-68-R68-R50-R48/22-R41-R37/38-R26-R24/25-R11
Safety Statements 26-28-36/37/39-45-61-28A-S61-S45-S36/37/39-S28A-S26-16
RIDADR UN 1143 6.1/PG 1
WGK Germany 3
RTECS GP9625000
9-13-23
HazardClass 6.1
PackingGroup I
Hazardous Substances Data123-73-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Crotonaldehyde English
SigmaAldrich English
ALFA English
Crotonaldehyde Usage And Synthesis
Chemical Propertiesclear liquid
General DescriptionWater-white to straw-colored liquid with a pungent, suffocating odor. Used as a chemical intermediate in a variety of industrial processes (surfactants, textiles, paper, fuels, insecticides, leather tanning, etc.). Used in chemical warfare.
Air & Water ReactionsHighly flammable.
Reactivity ProfileCrotonaldehyde is an aldehyde. Crotonaldehyde can react violently with strong oxidizing reagents, e.g., reaction with conc. nitric acid leads to instantaneous ignition [Andrussow, L., Chim. Ind. (Paris), 1961, 86, p. 542]. In contact with strong acids or bases Crotonaldehyde will undergo an exothermic condensation reaction. Reaction with 1,3-butadiene is particularly violent [Greenlee, K. W., Chem. Eng. News, 1948, 26, p. 1985]. Crotonaldehyde may rapidly polymerize with ethyl acetoacetate (Soriano, D.S. et al. 1988. Journal of Chemical Education 65:637.).
Health HazardAlthough slightly less toxic, crotonaldehyde is similar chemically and toxicologically to acrolein, which is rated as extremely toxic. Toxic concentrations for human inhalation have been reported at 12 mg/m3/10 minutes. Irritant dose to human eye is 45 ppm. As with acrolein, vapor exposures cause severe and painful eye irritation, damage to cornea, lacrimation (tearing), irritation of nasal membranes, pulmonary edema (filling of lungs with fluid) and gastrointestinal distress when ingested.
Fire HazardVapors form explosive mixtures in air or in sewers. Hazardous peroxides and acids emitted when heated to decomposition. Avoid nitric acid. Unstable, avoid oxygen, heat, elevated pressures. Hazardous polymerization may occur. Avoid contact with alkaline materials such as caustic ammonia or amines, or at elevated temperatures.
Tag:Crotonaldehyde(123-73-9) Related Product Information
Platinum bis(acetylacetonate) Ferric acetylacetonate Ruthenium acetylacetonate Manganic acetylacetonate Aluminum acetylacetonate LANTHANUM ACETYLACETONATE 2,4-PENTANEDIONE, SILVER DERIVATIVE Crotonaldehyde, 3-methyl-,3-Methyl-2-Crotonaldehyde Crotonaldehyde Fumaric acid Maleic anhydride 10-Undecenal Crotonic acid 2-BUTENE Maleic acid CROTONALDEHYDE,REAGENT,CROTONALDEHYDE (controlled ),2-butenal (=crotonaldehyde),CROTONALDEHYDE [154.2.28],Crotonaldehyde, mixture of cis and trans,crotonaldehyde,inhibite POLY(1-BUTENE) HEXOBARBITAL