Ethyl chloroacetate

Ethyl chloroacetate Property

mp : -26 °C bp : 143 °C(lit.) density : 1.15 vapor pressure : 10 mm Hg ( 38 °C) refractive index : n20/D 1.421(lit.) Fp : 150 °F storage temp. : Flammables area Water Solubility : 20 g/L (20 ºC) Merck : 14,3783 BRN : 506455 Stability:: Stable. Incompatible with acids, bases, oxidizing agents, reducing agents. Flammable. CAS DataBase Reference: 105-39-5(CAS DataBase Reference) NIST Chemistry Reference: Ethyl chloroacetate(105-39-5) EPA Substance Registry System: Acetic acid, chloro-, ethyl ester(105-39-5)

Safety

Hazard Codes : T,N Risk Statements : 23/24/25-50-10 Safety Statements : 45-61-7/9-16 RIDADR : UN 1181 6.1/PG 2 WGK Germany : 2 RTECS : AF9110000 HazardClass : 6.1 PackingGroup : II Hazardous Substances Data: 105-39-5(Hazardous Substances Data)

Ethyl chloroacetate Chemical Properties,Usage,Production

Chemical Properties colourless liquid Usage Reagent used in the preparation of 5 member heterocycles. General Description A clear colorless liquid with a pungent odor. Flash point 100°F. Denser than water and insoluble in water. Vapors heavier than air. Air & Water Reactions Highly flammable. Slow hydrolysis to acidic products will cause slow corrosion of common metals. No hazard involved. [USCG, 1999]. Reactivity Profile Ethyl chloroacetate is a chlorinated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Health Hazard Inhalation causes irritation of mucous membrane, headache, and nausea. Contact with liquid causes extreme eye irritation and conjunctivitis; irritates skin if not removed at once. Ingestion causes irritation of mouth and stomach. Fire Hazard Special Hazards of Combustion Products: Irritating, toxic hydrogen chloride and phosgene may be generated in fires.

Ethyl chloroacetate Preparation Products And Raw materials

Raw materials Calcium chloride Sodium bicarbonate

Preparation Products 2-PHENYLPROPIONALDEHYDE CARBOCROMENE HYDROCHLORIDE 3-(1，1-dimethylethyl)-5-(ethoxycarboxy)-methylthio-1，2，4-triazole (4-OXO-6,7-DIHYDRO-4H,5H-CYCLOPENTA[4,5]THIENO-[2,3-D]PYRIMIDIN-3-YL)-ACETIC ACID Piroxicam 2-(4-isobutylphenyl)propionaldehyde GIRARD'S REAGENT P 7-Methoxybenzofuran-2-carboxylic acid Piracetam 4-(ACETYLAMINO)PHENOXYACETIC ACID ETHYL ESTER 2-METHYLUNDECANAL ETHYL 3-(4-ISOBUTYLPHENYL)-3-METHYL GLYCIDATE AZIDITHION 6-Bromoindole-2-carboxylic acid Ethyl fluoroacetate 1-Boc-3-oxopiperazine Piperazin-2-one Etomidate ETHYL 5-BROMOTHIOPHENE-2-CARBOXYLATE Pseudothiohydantoin 2-(4-isobutylphenyl)propionaldehyde oxime SODIUM 3-4-ISOBUTYLPHENYL)-2,3-EPOXYBUTYURATE Ethyl 6-bromoindole-2-carboxylate ETHYL 3-PHENYLGLYCIDATE Chloroacetamide 5-Bromothiophene-2-carbohydrazide Cloricromene (6-ETHYL-4-OXO-4H-THIENO[2,3-D]PYRIMIDIN-3-YL)-ACETIC ACID 6-AMINO-CHROMEN-2-ONE 7-PROPOXY-CHROMEN-2-ONE Nitrofurantoin A-METHYL-3-PHENOXYBENZENEACETALDEHYDE VITAMIN A TRIETHYL 1,1,2-ETHANETRICARBOXYLATE Ethyl 2-aminothiazole-5-carboxylate Methyl 3-methyl-2-butenoate Ethyl 3-methyl-3-phenylglycidate 2-(2-thienyl)propionic acid Girard's Reagent T

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