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Methyl bromoacetate

CAS No.96-32-2
Chemical Name:Methyl bromoacetate
Synonyms:BAM;Methyl bomoacetate;BROMO METHYLACETATE;METHYL BROMOACETATE;METHYL 2-BROMOACETATE;2-BROMOMETHYL ACETATE;methylmonobromoacetate;BroMine Methyl acetate;Methyl monobromoacetate;Bromoacetic acid methyl
CBNumber:CB7171783
Molecular Formula:C3H5BrO2
Formula Weight:152.97
MOL File:96-32-2.mol
Methyl bromoacetate Property
mp : -50°C
bp : 51-52 °C15 mm Hg(lit.)
density : 1.616 g/mL at 25 °C(lit.)
refractive index : n20/D 1.458(lit.)
Fp : 145 °F
storage temp. : Store at R.T.
FreezingPoint : <-50℃
BRN : 506256
CAS DataBase Reference: 96-32-2(CAS DataBase Reference)
NIST Chemistry Reference: Acetic acid, bromo-, methyl ester(96-32-2)
EPA Substance Registry System: Acetic acid, bromo-, methyl ester(96-32-2)
Safety
Hazard Codes : T,Xi,F
Risk Statements : 25-34-37-23/24/25-40-36/37/38-38
Safety Statements : 26-36/37/39-45-28A-36-16
RIDADR : UN 2643 6.1/PG 2
WGK Germany : 3
RTECS : AF6300000
F : 19
HazardClass : 6.1
PackingGroup : II
HS Code : 29159080

Methyl bromoacetate Chemical Properties,Usage,Production

Chemical Properties
Colorless liquid
General Description
A colorless to straw-colored liquid with a sharp penetrating odor. Denser than water and soluble in water. Severly irritates skin and eyes. Toxic by ingestion and inhalation. Used to make vitamins and pharmaceuticals.
Air & Water Reactions
Highly flammable. Soluble in water.
Reactivity Profile
Methyl bromoacetate is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Health Hazard
TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
Methyl bromoacetate Preparation Products And Raw materials
Raw materials
Carbon tetrachloride Bromoacetic acid
Preparation Products
3-Ketomorpholine DIMETHYLAMINOACETYL CHLORIDE HYDROCHLORIDE Methyl 1H-indole-2-carboxylate METHYL 6-(TRIFLUOROMETHYL)-1H-INDOLE-2-CARBOXYLATE 4-CHLOROPHENOXYACETYL CHLORIDE
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BAM BROMO METHYLACETATE BROMOACETIC ACID METHYL ESTER METHYL 2-BROMOACETATE METHYL BROMOACETATE METHYL ALPHA-BROMOACETATE 96-32-2 Carbonyl Compounds C2 to C5 Building Blocks 2-BROMOACETIC ACID METHYL ESTER 2-BROMOMETHYL ACETATE Organic Building Blocks Esters Aceticacid,bromo-,methylester bromo-aceticacimethylester Methyl bomoacetate Methyl monobromoacetate Methylester kyseliny bromoctove methylesterkyselinybromoctove methylmonobromoacetate ACETATE Methyl bromoacetate, 97+% CH2BrCOOCH3 BrCH2COOCH3 Organics Methyl bromoacetate, 98+% C2 to C5 Carbonyl Compounds Esters Methyl bromoacetate solution 500 Series Drinking Water Methods BromoEPA Chemical Class Halogenated Method 552 Bromoacetic acid methyl BrCH2CO2CH3 Methyl bromoacetate,99% Methyl broMoacetate, 99% 100GR Methyl broMoacetate, 99% 25GR Building Blocks C2 to C5 Carbonyl Compounds Chemical Synthesis Organic Building Blocks Methyl BroMoacetate(Methyl 2-BroMoacetate Methyl broMoacetate 97% BroMine Methyl acetate
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