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78-67-1

78-67-1 Structure

78-67-1 Structure
IdentificationMore
【Name】

2,2'-Azobis(2-methylpropionitrile)
【CAS】

78-67-1
【Synonyms】

2,2'-AZOBIS(2-METHYLPROPIONITRILE)
2,2-AZOBIS(2-METHYLPROPIONITRILE)
2,2'-AZOBISISOBUTYRONITRILE
2,2'-AZODIISOBUTYRONITRILE
2,2'-dicyano-2,2'-azopropane
2,2'-Dimethyl-2,2'-azodipropionitrile
A,A'-AZOISOBUTYRONITRILE
AIBN
ALPHA,ALPHA'-AZOBISISOBUTYRONITRILE
ALPHA,ALPHA-AZOBISISOBUTYRONITRILE
ALPHA,ALPHA'-AZO-DI-ISO-BUTYRONITRILE
ALPHA,ALPHA'-AZOISOBUTYRONITRILE
AZOBISISOBUTYRONITRILE
azodiisobutyrodinitrile
AZODI-ISO-BUTYRONITRILE
AZOISOBUTYRONITRILE
VAZO(R) CATALYST 64 FREE RADICAL SOURCE
2,2’-Azobis(2-cyanopropane)
2,2’-azobis(2-methyl-propanenitril
2,2’-azobis(2-methyl-Propanenitrile
【EINECS(EC#)】

201-132-3
【Molecular Formula】

C8H12N4
【MDL Number】

MFCD00013808
【Molecular Weight】

164.21
【MOL File】

78-67-1.mol
Chemical PropertiesBack Directory
【Appearance】

white solid
【mp 】

102-104 °C (dec.)(lit.)
【density 】

1.11
【storage temp. 】

2-8°C
【Stability:】

Stability Flammable solid. Shock sensitive. Thermally unstable. May be explosive in combination with acetone or heptane. Incompatible with oxidizing agents.
【Water Solubility 】

Insoluble
【Merck 】

13,920
【CAS DataBase Reference】

78-67-1(CAS DataBase Reference)
【NIST Chemistry Reference】

2,2'-Azo-bis-isobutyronitrile(78-67-1)
【EPA Substance Registry System】

78-67-1(EPA Substance)
Safety DataBack Directory
【Hazard Codes 】

E,Xn
【Risk Statements 】

R2:Risk of explosion by shock, friction, fire or other sources of ignition.
R11:Highly Flammable.
R20/22:Harmful by inhalation and if swallowed .
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
【Safety Statements 】

S39:Wear eye/face protection .
S41:In case of fire and/or explosion do not breathe fumes .
S47:Keep at temperature not exceeding ... E C (to be specified by the manufacturer) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
【RIDADR 】

UN 3234 4.1
【WGK Germany 】

2
【RTECS 】

UG0800000
【F 】

4.4
【HazardClass 】

4.1
【PackingGroup 】

II
【Hazardous Substances Data】

78-67-1(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
【Raw materials】

Acetone-->Chlorine-->Hydrazinium hydroxide-->Sodium cyanide-->Sodium hypochlorite-->Acetone cyanohydrin -->BUTYRONITRILE
【Preparation Products】

4-(PYRROLIDIN-1-YLMETHYL)BENZENEBORONIC ACID, PINACOL ESTER 97%1-[4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZYL]PYRROLIDINE-->4-(2-CYANOETHYLAMINOCARBONYL)PHENYLBORONIC ACID-->2,1,3-Benzothiadiazole-5-carbaldehyde-->3-(2-CYANOETHYLAMINOCARBONYL)PHENYLBORONIC ACID-->4-(PIPERIDINE-1-CARBONYL)PHENYLBORONIC ACID-->2,1,3-Benzothiadiazol-5-ylmethanol-->3-(PIPERIDINOMETHYL)BENZALDEHYDE-->4-(1,2,3-THIADIAZOL-4-YL)BENZYLAMINE HYDROCHLORIDE-->3-PHENOXYPHENYLACETONITRILE-->2,6-Dichlorobenzaldehyde-->5-Dibenzosuberenone-->2-Chlorobenzyl chloride-->4-(1,2,3-THIADIAZOL-4-YL)BENZALDEHYDE-->3-QUINOLIN-2-YLPROPANOIC ACID-->Dichloroacetyl chloride-->Dicofol-->4-Benzofurazancarboxaldehyde-->2-(DIPHENYLPHOSPHINO)ETHYLTRIETHOXYSILANE-->5-(BROMOMETHYL)-2,1,3-BENZOTHIADIAZOLE-->11b,21-Dihydroxy-2'-methyl-5'bH-pregna-1,4-dieno[17,16-d]oxazole-3,20-dione 21-acetate-->Dideoxyinosine-->graft copolymer PAA-G-PIPA microsphere-->2-(Bromomethyl)benzoic acid-->2-TRIFLUOROMETHYLQUINOLINE-7-CARBOXYLIC ACID-->4-[4-(BROMOMETHYL)PHENYL]-1,2,3-THIADIAZOLE-->3-CHLORO-4-((CYCLOPROPYLAMINO)METHYL)BENZALDEHYDE-->METHYL ALPHA-BROMO-2-CHLOROPHENYLACETATE-->Maleic acid-allyl alcohol copolymer-->11-Bromoundecanoic acid-->1-(3-CHLORO-4-((CYCLOPROPYLAMINO)METHYL)PHENYL)ETHANONE-->2,4-Dichlorobenzyl chloride-->super absorbent resin synthesized by microwave cation ion radiation-->3,7-dichloro-8-dichloro methyl quinoline-->METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE-->dimethylacrolyl phenoxy propanestyrene copolymer optical plastics-->2-Nitroacetophenone-->amphoteric super absorbent resin synthesized by microwave radiation-->FTHALIDE
Hazard InformationBack Directory
【General Description】

Insoluble in water and denser than water. Moderately toxic by ingestion. Readily ignited by sparks or flames. Burns intensely and persistently. Toxic oxides of nitrogen produced during combustion. Used as a catalyst, in vinyl polymerizations and a blowing agent for plastics.
【Reactivity Profile】

Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. Self-accelerating decomposition may occur if the specific control temperature is not maintained. These materials are particularly sensitive to temperature rises. AZODIISOBUTYRONITRILE(78-67-1) is an azo compound. Azo, diazo, azido compounds can detonate. This applies in particular to organic azides that have been sensitized by the addition of metal salts or strong acids. Toxic gases are formed by mixing materials of this class with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.
【Air & Water Reactions】

Dust may form an explosive mixture in air. Insoluble in water.
Material Safety Data Sheet(MSDS)Back Directory
【msds information】

Azodiisobutyrodinitrile(78-67-1).msds
Spectrum DetailBack Directory
【Spectrum Detail】

2,2'-Azobis(2-methylpropionitrile)(78-67-1)1HNMR
2,2'-Azobis(2-methylpropionitrile)(78-67-1)IR3
2,2'-Azobis(2-methylpropionitrile)(78-67-1)13CNMR
2,2'-Azobis(2-methylpropionitrile)(78-67-1)IR2
2,2'-Azobis(2-methylpropionitrile)(78-67-1)IR1
2,2'-Azobis(2-methylpropionitrile)(78-67-1)MS
Well-known Reagent Company Product InformationBack Directory
【Acros Organics】

2,2'-Azobis(2-methylpropionitrile), 98%(78-67-1)
【Sigma Aldrich】

78-67-1(sigmaaldrich)
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