Identification | More | 【Name】
Tetramethylammonium hydroxide | 【CAS】
75-59-2 | 【Synonyms】
N,N,N-TRIMETHYLMETHANAMINIUM HYDROXIDE TETRAMETHYLAMMONIUM HYDROXIDE TMAH hydroxydedetetramethylammonium megapositcd14 Methanaminium,N,N,N-trimethyl-,hydroxide n,n,n-trimethyl-methanaminiuhydroxide nmd3 nmw-w ocg945 tetramethyl-ammoniuhydroxide tetramethylammoniumhydroxide,10%solutioninwater tetramethylammoniumhydroxide,solution TETRAME-AMMONIUMHYDROXIDE/H20 Tetramethyl ammonium Tetramethylaminonium hydroxide TETRAMETHYLAMMONIUM HYDROXIDE, 10 WT. % SOLUTION IN WATER TETRAMETHYLAMMONIUM HYDROXIDE SOL., 6% IN PROPYLENEGLYCOL TETRAMETHYLAMMONIUM HYDROXIDE, 1.0M SOLN . IN H2O, A.C.S. REAGENT TETRAMETHYLAMMONIUM HYDROXIDE SOLUTION, ~10% IN WATER | 【EINECS(EC#)】
200-882-9 | 【Molecular Formula】
C4H13NO | 【MDL Number】
MFCD00008280 | 【Molecular Weight】
91.15 | 【MOL File】
75-59-2.mol |
Chemical Properties | Back Directory | 【Appearance】
colourless to yellow liquid | 【mp 】
°C | 【bp 】
110 °C
| 【density 】
0.866 g/mL at 25 °C
| 【vapor pressure 】
17.5 mm Hg ( 20 °C)
| 【refractive index 】
n20/D 1.384
| 【Fp 】
80 °F
| 【storage temp. 】
2-8°C
| 【Stability:】
Stable. Flammable. Incompatible with strong oxidizing agents, strong acids. | 【Sensitive 】
Air Sensitive | 【Merck 】
14,9224 | 【BRN 】
3558708 | 【CAS DataBase Reference】
75-59-2(CAS DataBase Reference) | 【EPA Substance Registry System】
75-59-2(EPA Substance) |
Safety Data | Back Directory | 【Hazard Codes 】
C,T,F | 【Risk Statements 】
R24/25:Toxic in contact with skin and if swallowed . R34:Causes burns. R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed . R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . R10:Flammable. R21/22:Harmful in contact with skin and if swallowed . R25:Toxic if swallowed. R21:Harmful in contact with skin. R11:Highly Flammable. R67:Vapors may cause drowsiness and dizziness. R36:Irritating to the eyes. | 【Safety Statements 】
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S16:Keep away from sources of ignition - No smoking . S36/37:Wear suitable protective clothing and gloves . | 【RIDADR 】
UN 3286 3/PG 2
| 【WGK Germany 】
1
| 【RTECS 】
PA0875000
| 【F 】
4.4-10-34 | 【HazardClass 】
3 | 【PackingGroup 】
II |
Hazard Information | Back Directory | 【General Description】
TETRAMETHYLAMMONIUM HYDROXIDE(75-59-2) is a solid in the hydrated form or a colorless liquid with a strong ammonia-like odor. TETRAMETHYLAMMONIUM HYDROXIDE(75-59-2) is soluble in water. TETRAMETHYLAMMONIUM HYDROXIDE(75-59-2) is corrosive to metals and tissue. | 【Reactivity Profile】
TETRAMETHYLAMMONIUM HYDROXIDE acts like a base. Bases are chemically similar to sodium hydroxide (NaOH) or sodium oxide (Na2O). They neutralize acids exothermically to form salts plus water. When soluble in water they give solutions having a pH greater than 7.0. Mixing these materials with water can generate troublesome amounts of heat as the base is dissolved or diluted. Bases react with certain metals (such as aluminum and zinc) to form oxides or hydroxides of the metal and generate gaseous hydrogen. Bases may initiate polymerization reactions in polymerizable organic compounds, especially epoxides). They may generate flammable and/or toxic gases with ammonium salts, nitrides, halogenated organics, various metals, peroxides, and hydroperoxides. Materials of this group often serve as catalysts. | 【Air & Water Reactions】
TETRAMETHYLAMMONIUM HYDROXIDE is soluble in water. | 【Health Hazard】
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. | 【Fire Hazard】
Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. |
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