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75-44-5

75-44-5 Structure

75-44-5 Structure
IdentificationMore
【Name】

PHOSGENE
【CAS】

75-44-5
【Synonyms】

Carbonyl chloride
PHOSGENE
Carbon dichloride oxide
Carbon oxychloride
carbondichlorideoxide
carbone(oxychlorurede)
carbone(oxychlorurede)(french)
Carbonic chloride
Carbonic dichloride
carbonicaciddichloride
carbonicchloride
Carbonicdichloride
carbonio(ossiclorurodi)
carbonoxychloride
Carbonyl dichloride
Carbonylchlorid
Carbonyldichlorid
carbonyldichloride
chlorformylchloride
Chloro-formyl
【EINECS(EC#)】

200-870-3
【Molecular Formula】

CCl2O
【MDL Number】

MFCD00036119
【Molecular Weight】

98.92
【MOL File】

75-44-5.mol
Chemical PropertiesBack Directory
【density 】

0.94 g/mL at 20 °C
【vapor pressure 】

1180 mm Hg ( 20 °C)
【Fp 】

4 °C
【storage temp. 】

2-8°C
【Merck 】

13,7421
【CAS DataBase Reference】

75-44-5(CAS DataBase Reference)
Safety DataBack Directory
【Hazard Codes 】

T+,F
【Risk Statements 】

R26:Very Toxic by inhalation.
R34:Causes burns.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R11:Highly Flammable.
【Safety Statements 】

S9:Keep container in a well-ventilated place .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
【RIDADR 】

UN 3384 6.1/PG 1
【WGK Germany 】

2
【RTECS 】

SY5600000
【F 】

3-21
【HazardClass 】

2.3
Raw materials And Preparation ProductsBack Directory
【Raw materials】

Carbon tetrachloride-->SULFURIC ACID-->Coke (coal)
【Preparation Products】

NAPROANILIDE-->Isoprocarb-->Methidathion-->Hexaflumuron-->Forchlorfenuron-->Diphenyl carbonate-->Oxadiazon-->Flufenoxuron-->Nicarbazin-->Methylaminoformyl chloride-->Iprodione-->Thiophanate-methyl -->2,2,2-Trichloroethyl chloroformate-->Isophorone diisocyanate -->3-Methyl-4-(methylthio)phenol-->2-(2-CHLOROETHOXY)-BENZENESULFONAMIDE-->ISAZOPHOS-->Cinosulfuron-->N-((4-Chlorophenyl)methyl)-N-cyclopentyl-N'-phenylurea-->Diuron-->Fluometuron-->TRIFLUMIZOLE-->Diisopropyl peroxydicarbonate-->Octadecanoyl chloride-->METOXADIAZONE-->bis(2-phenoxyethyl) peroxydicarbonate -->3,4,5-TRIMETHACARB-->Isocyanatocyclohexane-->2-Benzothiazolol-->Eradicane-->Direct Red 75 tetrasodium salt -->o-ethoxy carbonyl benzene sulfonyl isocyanate-->4-Chlorophenyl isocyanate-->3-Chlorophenyl isocyanate-->Prochloraz-->Iminodibenzylcarbonyl chloride-->Oxcarbazepine-->Polymethylene polyphenyl polyisocyanate-->4,4'-Bis(diethylamino) benzophenone-->tetrasodium 4,4'-[carbonylbis[imino(5-methoxy-2-methyl-4,1-phenylene)azo]]bis[5-hydroxynaphthalene-2,7-disulphonate]
Material Safety Data Sheet(MSDS)Back Directory
【msds information】

Phosgene(75-44-5).msds
Hazard InformationBack Directory
【Reactivity Profile】

PHOSGENE is water reactive. Incompatible with strong oxidizing agents, alcohols, amines, alkali. May react violently with aluminum, alkali metals (lithium, potassium, sodium), alcohols (isopropyl alcohol, 2,4-hexadiyn-1,6-diol), sodium azide [Bretherick, 5th ed., 1995, p. 134]. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. Phosgene reacts with phosphate or silicate salts, yielding water-reactive and toxic POCl3 with phosphates (Dunlap, K.L. 2005. Phosgene. In Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc.).
【Air & Water Reactions】

Decomposes slowly in water or moist air (or when inhaled) to form very corrosive hydrogen chloride gas (hydrochloric acid) and carbon monoxide.
【Health Hazard】

Phosgene is a lung toxicant that causes damage to the capillaries, bronchioles and alveoli of the lungs, by decomposition to hydrochloric acid. There is little immediate irritant effect upon the respiratory tract, and the warning properties of the gas are therefore very slight. Pulmonary edema, bronchopneumonia and occasionally lung abscesses develop. Degenerative changes in the nerves have been reported as later developments. A concentration of 25 ppm is dangerous for exposures lasting 30-60 minutes and 50 ppm is rapidly fatal after even short exposure.
【Fire Hazard】

When heated to decomposition or on contact with water or steam, PHOSGENE will react to produce toxic and corrosive fumes. Reacts violently with aluminum; tert-butyl azido formate; 2,4-hexadiyn-1,6-diol; isopropyl alcohol; potassium; sodium; hexafluoro isopropylidene; amino lithium; lithium. Stable in steel containers if dry. Avoid moisture.
Well-known Reagent Company Product InformationBack Directory
【Sigma Aldrich】

75-44-5(sigmaaldrich)
Company Name:Shanghai Hanhong Chemical Co., Ltd.  
Telephone:021-61521197,021-60496702,021-54302127,021-54306202,021-61525701,021-54308259
Contact Fax:+86-21-54291107
Website:www.hanhonggroup.com
Company Name:(CSR Factory)China Skyrun Industrial CO.,ltd  
Telephone:info@chinaskyrun.com
Contact Fax:manager@chinaskyrun.com
Website:www.chinaskyrun.com
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24424-99-5 33842-02-3 463-71-8 94334-64-2 32315-10-9 75-44-5