| Identification | More | 【Name】
Lithium diisopropylamide | 【CAS】
4111-54-0 | 【Synonyms】
DIISOPROPYLAMINOLITHIUM
LDA
LDA THF COMPLEX
LITHIUM DIISOPROPYLAMIDE
LITHIUM DIISOPROPYLAMIDE THF COMPLEX
LITHIUM DIISOPROPYLAMINE
2-Propanamine,N-(1-methylethyl)-,lithiumsalt
n-(1-methylethyl)-2-propanaminlithiumsalt
Lithium diisopropylamide solution
Lithium dlisopropylamide
LITHIUM DIISOPROPYLAMIDE, 10 WT. % SOLUT ION IN MINERAL OIL
LITHIUM DIISOPROPYLAMIDE, 2.0M SOLUTION IN HEPTANE/THF/ETHYLBENZENE
LITHIUM DIISOPROPYLAMIDE, 1.8M SOLUTION IN THF/HEPTANE/ETHYLBENZENE
LITHIUM DIISOPROPYLAMIDE, 10 WT. % SUSPE NSION IN HEXANES
Lithium diisopropylamide solution, ~2 M in THF/heptane/ethylbenzene
LITHIUM DIISOPROPYLAMIDE, 2M SOLUTION IN THF/HEPTANE
Lithium diisopropylamide, 2M solution in THF/n-heptane/ethylbenzene
LITHIUMDIISOPROPYLAMIDE,2MSOLUTIONINTETRAHYDROFURAN/HEPTANE/ETHYLBENZENE
lithium diisopropylamide (LDA)
LITHIUM DIISOPROPYLAMIDE, 2M SOLUTION IN THF/N-HEPTANE | 【EINECS(EC#)】
223-893-0 | 【Molecular Formula】
C6H14LiN | 【MDL Number】
MFCD00064449 | 【Molecular Weight】
107.12 | 【MOL File】
4111-54-0.mol |
| Chemical Properties | Back Directory | 【Appearance】
dark yellow to orange or dark red-brown solution | 【bp 】
65 °C
| 【density 】
0.864 g/mL at 25 °C(lit.)
| 【vapor density 】
>1 (vs air)
| 【Fp 】
91 °F
| 【storage temp. 】
2-8°C
| 【form 】
liquid
| 【color 】
brown
| 【Water Solubility 】
decomposes | 【Merck 】
3196 | 【Detection Methods】
T | 【CAS DataBase Reference】
4111-54-0(CAS DataBase Reference) | 【Storage Precautions】
Air sensitive;Store under nitrogen;Moisture sensitive | 【EPA Substance Registry System】
4111-54-0(EPA Substance) |
| Safety Data | Back Directory | 【Hazard Codes 】
C,N,F | 【Risk Statements 】
R14:Reacts violently with water.
R17:Spontaneously flammable in air.
R34:Causes burns.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R35:Causes severe burns.
R19:May form explosive peroxides.
R15:Contact with water liberates extremely flammable gases.
R11:Highly Flammable.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R14/15:Reacts violently with water, liberating extremely flammable gases .
R10:Flammable.
R40:Limited evidence of a carcinogenic effect.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . | 【Safety Statements 】
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S8:Keep container dry .
S16:Keep away from sources of ignition - No smoking .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S33:Take precautionary measures against static discharges .
S27:Take off immediately all contaminated clothing . | 【RIDADR 】
UN 3399 4.3/PG 2
| 【WGK Germany 】
3
| 【F 】
1-10 | 【HazardClass 】
4.2 | 【PackingGroup 】
I |
| Raw materials And Preparation Products | Back Directory | 【Preparation Products】
3-FURANMETHANOL-->6-FLUORO-1H-PYRAZOLO[3,4-B]PYRIDINE-3-CARBONITRILE-->ETHYL 3-FUROATE-->4-METHOXY-1H-PYRROLO[2,3-B]PYRIDINE-2-CARBALDEHYDE-->2-(4-METHOXY-1H-PYRROLO[2,3-B]PYRIDIN-2-YL)ETHANAMINE-->(4-METHOXY-1H-PYRROLO[2,3-B]PYRIDIN-2-YL)METHANOL-->ETHYL 4-METHOXY-1H-PYRROLO[2,3-B]PYRIDINE-2-CARBOXYLATE-->6-FLUORO-1H-PYRAZOLO[3,4-B]PYRIDINE-3-CARBOXYLIC ACID-->5-AMINO-2-METHOXY-ISONICOTINIC ACID-->3-FLUOROQUINOLINE-4-CARBOXYLIC ACID-->3,5-DIFLUOROPYRIDINE-4-CARBALDEHYDE-->2-Chloro-4-iodopyridine-3-carboxaldehyde-->1-(2,6-DIFLUOROPYRIDIN-3-YL)PROPAN-1-ONE-->3-BROMOTHIOPHENE-2-CARBOXAMIDE-->5-FLUORO-2-METHOXYPYRIDINE-4-BORONIC ACID-->1H-Azepine-3-carboxylicacid,hexahydro-,methylester(9CI)-->5-BROMO-2-FLUOROPYRIDINE-3-CARBALDEHYDE-->3-Bromothiophene-2-carbaldehyde-->Rimonabant hydrochloride-->Ethyl 2-oxocyclopentylacetate-->2-Fluoro-3-pyridylboronic acid-->4-ALLYL-PIPERIDINE-1,4-DICARBOXYLIC ACID MONO-TERT-BUTYL ESTER-->3-Chlorothiophene-2-carboxylic acid-->1-(PHENYLSULFONYL)-1H-INDOLE-2-CARBALDEHYDE-->4-Chloronicotinic acid-->2-Methoxypyridine-3-boronic acid-->3-FLUORO-2-IODOPYRIDINE-4-CARBOXYLIC ACID-->3-BROMOTHIOPHENE-2-CARBONYL CHLORIDE-->3-Chlorothiophene-2-carbonyl chloride |
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