1-Methyl-3-nitro-1-nitrosoguanidine

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Products Intro: Product Name:1-Methyl-3-nitro-1-nitrosoguanidine (wetted with ca. 50% Water, containing 5g on a dry weight basis)
CAS:70-25-7
Purity:95.0%(T) Package:5G
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Products Intro: Product Name:1-Methyl-3-nitro-1-nitrosoguanidine
CAS:70-25-7
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Products Intro: Product Name:N-Methyl-N'-nitro-N-nitrosoguanidine
CAS:70-25-7
Purity:100 μg/ML in Toluene Package:50Mg
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Products Intro: Product Name:N-Methyl-N'-nitro-N-nitrosoguanidine
CAS:70-25-7
Purity:50% water wet Package:5g Remarks:AAA123681
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Products Intro: Product Name:N-Methyl-N'-nitro-N-nitrosoguanidine
CAS:70-25-7
Purity:98% HPLC Package:1g;5g;25g;100g
1-Methyl-3-nitro-1-nitrosoguanidine Basic information
Product Name:1-Methyl-3-nitro-1-nitrosoguanidine
Synonyms:1-METHYL-3-NITRO-1-NITROSOGUANIDINE;DIAZOMETHANE PRECURSOR;MNNG;N-METHYL-N'-NITRO-N-NITROSOGUANIDINE;N-METHYL-N-NITROSO-N'-NITROGUANIDINE;1-Methyl-1-Nitroso-3-nitroguanidine;1-methyl-3-nitro-1-nitroso-guanidin;1-nitroso-3-nitro-1-methylguanidine
CAS:70-25-7
MF:C2H5N5O3
MW:147.09
EINECS:200-730-1
Product Categories:Diazomethane Precursors & Equivalents (GC Derivatizing Reagents);Analytical Chemistry;Esterification & Alkylation (GC Derivatizing Reagents);GC Derivatizing Reagents;Mutagenesis Research Chemicals
Mol File:70-25-7.mol
1-Methyl-3-nitro-1-nitrosoguanidine Structure
1-Methyl-3-nitro-1-nitrosoguanidine Chemical Properties
mp 118°C (dec.)
storage temp. 0-6°C
Water Solubility Reacts violently
Merck 6103
Stability:Unstable. Reacts violently with water. May detonate under impact. Heat, light and moisture sensitive. May explode if stored in sealed ampules. Highly flammable. Incompatible with aqueous solutions, acids, bases, oxidizing agents, reducing agents. Alkaline hydrolysis releases toxic and explosive gases.
CAS DataBase Reference70-25-7(CAS DataBase Reference)
NIST Chemistry ReferenceGuanidine, n-methyl-n'-nitro-n-nitroso-(70-25-7)
EPA Substance Registry SystemGuanidine, N-methyl-N'-nitro-N-nitroso- (70-25-7)
Safety Information
Hazard Codes T;N,N,T
Risk Statements 45-20-36/38-51/53
Safety Statements 53-45-61
RIDADR 2926
RTECS MF4200000
HazardClass 4.1
PackingGroup II
Hazardous Substances Data70-25-7(Hazardous Substances Data)
MSDS Information
1-Methyl-3-nitro-1-nitrosoguanidine Usage And Synthesis
Chemical Propertiesyellow to pink crystals
UsageA DNA-damaging agent, used as a positive control in SHE cell transformation assays.
General DescriptionA yellow powder. Melting point 244°F. Decomposes above 212°F. A suspected carcinogen. Extremely hazardous as a mutagen. Avoid skin contact and inhalation of of vapors. Usually stored frozen (below 32°F) in polyethylene bottles that are tightly closed and contained in a metal can. May decomposed during prolonged storage and develop sufficient pressure in a closed container to explode. Keep away from heat, sparks, and open flame.
Air & Water ReactionsHighly flammable. Reacts violently with water .
Reactivity Profile1-Methyl-3-nitro-1-nitrosoguanidine will detonate under high impact. 1-Methyl-3-nitro-1-nitrosoguanidine is sensitive to heat. A sample has exploded when melted in a sealed capillary tube. Incompatible with acids, bases, oxidizing agents and reducing agents. Reacts with bases to release highly toxic, irritating and explosive gases. Reacts slowly with acids to release nitrous acid. Reacts with various nucleophiles, especially amines and thiols. Reacts with aqueous potassium hydroxide to form a highly reactive compound. The crude product from aqueous nitrosation is pyrophoric but recrystallized material is stable .
Health HazardFire may produce irritating and/or toxic gases. Contact may cause burns to skin and eyes. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
Fire HazardFlammable/combustible material. May be ignited by friction, heat, sparks or flames. Some may burn rapidly with flare burning effect. Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence. Substance may be transported in a molten form at a temperature that may be above its flash point. May re-ignite after fire is extinguished.
1-Methyl-3-nitro-1-nitrosoguanidine Preparation Products And Raw materials
Raw materialsEtanol-->Methanol-->Sulfuric acid -->Nitric acid-->Sodium nitrite-->1-Butanol-->METHYLAMINE-->2-Methyl-2-thiopseudourea sulfate-->Cyanamide-->Nitroguanidine-->1-Methyl-3-nitroguanidine
Tag:1-Methyl-3-nitro-1-nitrosoguanidine(70-25-7) Related Product Information
2-[[[[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid methyl ester N-ETHYL-N'-NITRO-N-NITROSOGUANIDINE 1-BUTYL-3-NITRO-1-NITROSOGUANIDINE N-methyl-N,N'-dinitroguanidine N'-NITRO-N-NITROSO-N-PROPYLGUANIDINE 1-Methyl-3-nitro-1-nitrosoguanidine Methanol Tetramethylguanidine Diazomethane Basic Violet 1 Kresoxim-methyl Methyl nitrotoluene Methylparaben Nitroguanidine Birch-Me Methyl acrylate Tribenuron methyl