SULFURIC ACID

SULFURIC ACID Suppliers list
Company Name:Alfa Aesar  
Tel:400-610-6006; 021-67582000
Email:saleschina@alfa-asia.com
Products Intro: Product Name:Sulfuric acid, 20% fuMing, 18-24% free SO{3}
CAS:8014-95-7
Package:100g Remarks:045543
Company Name:Beijing dtftchem Technology Co., Ltd.  
Tel:13651141086; 86(10)60275028、60275820
Email:dtftchem@sina.com
Products Intro: CAS:8014-95-7
Purity:50.00%
Company Name:Beijing Ouhe Technology Co., Ltd  
Tel:+86-10-4006331231;+86-10-51280831;+86-10-82967028
Email:sales@ouhechem.com
Products Intro: Product Name:SULFURIC ACID
CAS:8014-95-7
Purity:98% Package:10g;50g;100g;250g;500g
Company Name:Shanghai Hanhong Chemical Co., Ltd.  
Tel:021-61521197,021-60496702,021-54302127,021-54306202,021-61525701,021-54308259
Email:jerry.ma@hanhonggroup.com
Products Intro: Product Name:sulphuric acid fuming
CAS:8014-95-7
Remarks:RA03000005
Company Name:Chengdu XiYa Chemical Technology Co., Ltd.  
Tel:4008-626-111
Email:sale@xiyashiji.com
Products Intro: Product Name:Sulfuric acid fuming
CAS:8014-95-7
Purity:99% HPLC Package:25g,100g,500g
SULFURIC ACID Basic information
Product Name:SULFURIC ACID
Synonyms:SICACIDE(R);SICACIDE, WITH INDICATOR;SILICA ANALYSER SOLUTION NO 3;SULFURIC ACID (1 AND 2);SULFURIC ACID, 3.5N;SULFURIC ACID BABCOCK;SULFURIC ACID STANDARD;SULFURIC ACID, FUMING
CAS:8014-95-7
MF:H2O7S2
MW:178.14
EINECS:231-639-5
Product Categories:Refined & Fuming Sulfuric Acid(Oleum);Fuming Sulfuric Acid
Mol File:8014-95-7.mol
SULFURIC ACID Structure
SULFURIC ACID Chemical Properties
mp 2 °C
bp ~290 °C(lit.)
density 1.840 g/mL at 25 °C(lit.)
vapor density <0.3 (25 °C, vs air)
vapor pressure 1 mm Hg ( 146 °C)
solubility H2O: soluble
Sensitive Hygroscopic
Merck 14,8974
Stability:Stable. Incompatible with organic materials, powdered metals, bases, halides. Reacts violently with water. Very hygroscopic.
CAS DataBase Reference8014-95-7(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 36/38-37-35-14-34
Safety Statements 26-30-45-36/37/39
RIDADR UN 3264 8/PG 3
WGK Germany 1
RTECS WS5600000
3
HazardClass 8
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
SULFURIC ACID Usage And Synthesis
Chemical Propertiesviscous liquid
General DescriptionThick fuming yellow liquid. Density 16.5 lb / gal. Very toxic by inhalation. Corrosive to metals and tissue, quickly causing severe burns. Used to make chemicals, dyes, explosives and in petroleum refining.
Air & Water ReactionsFumes in air. Soluble in water; dissolution generates dangerous amounts of heat that can cause localized boiling and spattering of the acidic mixture and generate heavy fumes. During sulfonation of mononitrobenzene with fuming sulfuric acid, a leak from an internal cooling coil permitted water to enter the reaction tank. A violent eruption occurred due to the heat of solution [MCA Case History 944(1963)].
Reactivity ProfileSULFURIC ACID reacts as a strong acid, as an oxidizing agent and as a dehydrating agent. Chars wood, sugar and many other organic materials on contact. The heat from these reactions may ignite the wood, sugar or organic matter. May react explosively with acetic acid, acetic anhydride, acetonitrile, acrolein, acrylic acid, acrylonitrile, allyl alcohol, allyl chloride, ammonium hydroxide, aniline, cresol, butyraldehyde, cumene, ethyl acetate, ethylene diamine, ethylene glycol, glyoxal, isoprene, isopropyl alcohol, methyl ethyl ketone, propylene oxide, pyridine, styrene, vinyl acetate; strong bases (sodium hydroxide, potassium hydroxide) or mineral acids (nitric acid, hydrochloric acid, hydrofluoric acid) [Lewis, 3rd ed., 1993, p. 1195]. Mixing in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: 2-aminoethanol, ammonium hydroxide (28%), chlorosulfonic acid, ethylenediamine, ethyleneimine, ethylene cyanohydrin, hydrochloric acid (36%), hydrofluoric acid (48.7%), isopropyl alcohol, nitric acid (70%), 2-nitropropane, propiolactone, propylene oxide, pyridine, styrene monomer, sodium hydroxide, sulfolane, vinyl acetate, vinylidene chloride [NFPA 1991]. Extremely hazardous in contact with carbides, bromates, chlorates, fulminates, picrates, and powdered metals. May induce violent polymerization in polymerizable organic compounds such as allyl chloride. Reacts exothermically with sodium hypochlorite to produce chlorine gas.
Health HazardAcid mist is irritating to eyes, nose and throat. Liquid causes severe burns of skin and eyes.
Fire HazardSpecial Hazards of Combustion Products: Toxic and irritating vapors are generated.
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