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ピバル酸

CAS番号.75-98-9
化学名:ピバル酸
别名:ピバル酸;ネオペンタン酸;tert-ペンタン酸;ピバリン酸;2,2-ジメチルプロピオン酸;2,2-ジメチルプロパン酸;トリメチル酢酸;トリメチル酢酸(ピバリン酸)
英語化学名:Pivalic acid
英語别名:versatic5;PA)Pivalic;PIVALIC ACID;Pivalinsαure;Pivaloylacid;tert-C4H9COOH;Versatic5acid;acidepivalique;Neopentylsαure;pivalinic acid
CBNumber:CB4244051
分子式:C5H10O2
分子量:102.13
MOL File:75-98-9.mol
ピバル酸 物理性質
融点 : 32-35 °C(lit.)
沸点 : 163-164 °C(lit.)
比重(密度) : 0.889 g/mL at 25 °C(lit.)
蒸気密度: 3.6 (vs air)
蒸気圧: 9.75 mm Hg ( 60 °C)
屈折率 : 1.393
闪点 : 147 °F
貯蔵温度 : 2-8°C
水溶解度 : 25 g/L (20 ºC)
Merck : 14,7511
BRN : 969480
CAS データベース: 75-98-9(CAS DataBase Reference)
NISTの化学物質情報: Pivalic acid(75-98-9)
EPAの化学物質情報: Propanoic acid, 2,2-dimethyl-(75-98-9)
安全性情報
主な危険性 : C
Rフレーズ : 21/22-34
Sフレーズ : 26-36/37/39-45
RIDADR : UN 3261 8/PG 2
WGK Germany : 1
RTECS 番号: TO7700000
国連危険物分類 : 8
容器等級 : II
有毒物質データの: 75-98-9(Hazardous Substances Data)

ピバル酸 化学特性,用途語,生産方法

化学的特性
white crystalline low melting mass
使用
Pivalic Acid is a metabolite of oral cephem (β-lactam) antibiotics such as S-1108, containing pivaloyl moieties.
一般的な説明
Pivalic acid is a colored crystalline solid of low toxicity that is soluble in water, ethyl alcohol and diethyl ether.
空気と水の反応
With mixing, water soluble.
反応プロフィール
Pivalic acid is a carboxylic acid. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in Pivalic acid to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.
健康ハザード
CALL FOR MEDICAL AID. SOLID: Irritating to eyes and skin. Harmful if swallowed. IF IN EYES OR ON SKIN, flush with running water for at least 15 minutes; hold eyelids open if necessary. Wash skin with soap and water. Remove and isolate contaminated clothing and shoes at the site. If SWALLOWED and victim is UNCONSCIOUS OR HAVING CONVULSIONS, do nothing except keep victim warm. Because of low volatility, it is relatively harmless when inhaled at normal ambient temperature (around 20°C). It is slightly toxic by ingestion or skin absorption. The vapor is irritating at elevated temperatures. Can cause considerable discomfort by oral routes; may cause reversible or irreversible changes to exposed tissue, not permanent injury or death.
火災危険
COMBUSTIBLE. Produces vapors irritating to eyes and skin. Decomposes to produce acrid smoke and fumes.
ピバル酸 上流と下流の製品情報
原材料
炭素オキシド 2-メチル-1-プロパノール 2-クロロ-2-メチルプロパン イソブテン ぎ酸 [一般有機合成用] 水質分析用標準溶液 クロロホルム (1mg/mL メタノール溶液) ピバロニトリル
準備製品
2-tert-ブチルピリジン-4-カルボニトリル 2-[(2-クロロフェニル)メチル]-4,4-ジメチルイソオキサゾリジン-3-オン 3-メトキシベンゼンプロパン酸 3-クロロピバリン酸 ピバロイルtert-ブチルペルオキシド ピバロイルクロリド
ピバル酸 生産企業      Global( 210)Suppliers     
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75-98-9(ピバル酸) キーワード:
ジメチルスルホキシド グリシン [電気泳動用] くえん酸 トリフルオロ酢酸 (約0.5mol/L水溶液) [イオン対試薬] ステアリン酸 葉酸水和物 N,N-ジメチルアセトアミド ピバロニトリル 2,2-ビス(ヒドロキシメチル)プロピオン酸 2-クロロプロピオン酸 トリフルオロ酢酸無水物 2,6-ルチジン ピバル酸メチル シリコーンゴム N,N-ジメチルホルムアミド トリアセチン ヒドロキシピバル酸 グリシルグリシルグリシン
75-98-9 RARECHEM AL BO 0076 NEOPENTANOIC ACID PIVALIC ACID TRIMETHYLACETIC ACID CARBOXYLIC ACID C5 ALPHA,ALPHA-DIMETHYLPROPIONIC ACID 2,2-DIMETHYLPROPIONIC ACID 2,2-DIMETHYLPROPANOIC ACID 2,2,2-Trimethylaceticacid 2,2-dimethyl-propanoicaci 2,2-dimethyl-propionicaci 2,2-Dimethylpropionsαure 2,3-Dimethylpropionsαure Acetic acid, trimethyl- acidepivalique Dimethylpropionic acid Kyselina 2,2-dimethylpropionova Kyselina pivalova kyselina2,2-dimethylpropionova kyselinapivalova Neopentylsαure Pivalinsαure Propanoic acid, 2,2-dimethyl- Propanoicacid,2,2-dimethyl- Propionic acid, 2,2-dimethyl- tert-C4H9COOH tert-Pentanoic Acid tert-pentanoicacid trimethyl-aceticaci Trimethylessigsαure ピバル酸 ネオペンタン酸 tert-ペンタン酸 ピバリン酸 2,2-ジメチルプロピオン酸 2,2-ジメチルプロパン酸 トリメチル酢酸 トリメチル酢酸(ピバリン酸)
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