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ChemicalBook >> CAS DataBase List >> 4-Hydroxy-4-methyl-2-pentanone

4-Hydroxy-4-methyl-2-pentanone

CAS No.123-42-2
Chemical Name:4-Hydroxy-4-methyl-2-pentanone
Synonyms:DAA;Pyraton;Pyranton;Tyranton;Diacetone;pyrantona;Pyranton a;Diacetonalcool;Diacetonalcohol;Diacetonalkohol
CBNumber:CB9783177
Molecular Formula:C6H12O2
Formula Weight:116.16
MOL File:123-42-2.mol
4-Hydroxy-4-methyl-2-pentanone Property
mp : -42.8 °C
bp : 166 °C(lit.)
density : 0.9385
vapor density : 4 (vs air)
vapor pressure : <1 mm Hg ( 20 °C)
refractive index : n20/D 1.423(lit.)
Fp : 132 °F
Water Solubility : MISCIBLE
Merck : 14,2964
BRN : 1740440
Stability:: Stable. Flammable. Incompatible with strong oxidizing agents, amines, ammonia, strong acids, strong bases, alkalies, aluminium.
CAS DataBase Reference: 123-42-2(CAS DataBase Reference)
NIST Chemistry Reference: 4-Hydroxy-4-methylpentan-2-one(123-42-2)
EPA Substance Registry System: 2-Pentanone, 4-hydroxy-4-methyl-(123-42-2)
Safety
Hazard Codes : Xi
Risk Statements : 36-R36
Safety Statements : 24/25-S24/25
RIDADR : UN 1148 3/PG 3
WGK Germany : 1
RTECS : SA9100000
F : 9
HazardClass : 3
PackingGroup : III
Hazardous Substances Data: 123-42-2(Hazardous Substances Data)

4-Hydroxy-4-methyl-2-pentanone Chemical Properties,Usage,Production

Chemical Properties
colourless liquid
General Description
A clear colorless liquid with a pleasant odor. Flash point below 141°F. Less dense than water. Vapors heavier than air.
Air & Water Reactions
Highly flammable. Soluble in water.
Reactivity Profile
Acetyl bromide reacts violently with alcohols or water, [Merck 11th ed., 1989]. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, [Chem. Eng. News 45(43):73(1967); J, Org. Chem. 28:1893(1963)]. Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous-carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites, [NFPA 491 M, 1991]. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence, [Wischmeyer(1969)].
Health Hazard
Vapor is irritating to the mucous membrane of the eye and respiratory tract. Inhalation can cause dizziness, nausea, some anesthesia. Very high concentrations have a narcotic effect. The liquid is not highly irritating to the skin but can cause dermatitis.
Fire Hazard
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
4-Hydroxy-4-methyl-2-pentanone Preparation Products And Raw materials
Raw materials
Acetone DOYLE DIRHODIUM CATALYST-RH2(4S-MEOX)4 Phthalic anhydride
Preparation Products
MESITYL OXIDE PAINT 4-Methyl-2-pentanol 2,4-DIMETHYL-3-CYCLOHEXENECARBOXALDEHYDE
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123-42-2(4-Hydroxy-4-methyl-2-pentanone)Related Search:
Thiophanate-methyl DIACETONE-D-GALACTOSE,DIACETONE-ALPHA-D-GAL 2-Pentanone Methyl acetate Kresoxim-methyl Mesotrione Birch-Me Parathion-methyl Ethyl acetate Acetonylacetone 1-Methylcyclopentanol 2-[[[[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid methyl ester 2,2',4,4'-Tetrahydroxybenzophenone DIACETONE ACRYLAMIDE CHLOROPHOSPHONAZO III Tribenuron methyl METHYLCYCLOPENTADIENE DIMER 2-Butanone
(CH3)2C(OH)CH2C(O)CH3 2-Hydroxy-2-methyl-4-pentanone 2-Methyl-3-pentanol-4-one 2-Methylpentan-2-ol-4-one 2-Pentanone, 4-hydroxy-4-methyl- 4-hydroxy-4-methyl-2-pentanon 4-hydroxy-4-methyl-2-pentanone(diacetonealcohol) 4-hydroxy-4-methylpentan- 4-Hydroxy-4-methyl-pentan-2-on 4-hydroxy-4-methyl-pentan-2-on(german,dutch) 4-Hydroxy-4-methylpentanone 4-Hydroxy-4-methylpentanone-2 4-hydroxyl-2-keto-4-methylpentane 4-Idrossi-4-metil-pentan-2-one 4-Methyl-2-pentanon-4-ol 4-Methyl-4-hydroxy-2-pentanone Acetonyldimethylcarbinol Diacetonalcohol Diacetonalcool Diacetonalkohol Diacetone diacetonealcool Diacetone-alcool diacetone-alcool(french) diacetonylalcohol Diketone alcohol diketonealcohol dimethylacetonylcarbinol Hydroxy-4-methyl-2-pentanone Pyranton Pyranton a pyrantona Pyraton Tyranton Organic Building Blocks Ketones TIMTEC-BB SBB009084 4-HYDROXY-2-KETO-4-METHYLPENTANE 4-HYDROXY-4-METHYL-2-PENTANONE 4-HYDROXY-4-METHYLPENTAN-2-ONE 2-METHYL-2-PENTANOL-4-ONE 123-42-2 Building Blocks Carbonyl Compounds C3 to C6 DAA DIACETONE ALCOHOL DiacetoneAlcoholForSynthesis DiacetoneAlcohol,Certified 4-Hydroxy-4-methylpentan-2-one, 98+% 4-Hydroxy-4-methyl-2-pentanone, 99+% 150609-95-1 CH3COCH2CCH32OH Industrial/Fine Chemicals 123422 CH3COCH2COHCH32 4-HYDROXY-4-METHYL-2-PENTANONE, SYNTHESIS GRADE 4-Hydroxy-4-methyl-2-pentanone, 98+%
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