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Hydrofluoric acid

CAS No.7664-39-3
Chemical Name:Hydrofluoric acid
Synonyms:HF;HF2;Rubigine;antisal2b;60% HF/DMF;Fluorowodor;caswellno484;Fluoric acid;hydrofluoric;Hydrofluoride
CBNumber:CB8380315
Molecular Formula:FH
Formula Weight:20.01
MOL File:7664-39-3.mol
Hydrofluoric acid Property
mp : -35°C
bp : 105°C
density : 1.15 g/mL at 25 °C(lit.)
vapor density : 1.27 (vs air)
vapor pressure : 25 mm Hg ( 20 °C)
Fp : 112°C
Water Solubility : soluble
Sensitive : Hygroscopic
Merck : 14,4790
Stability:: Stable. Hygroscopic. Incompatible with glass, alkali metals, light metals, alkaline earth metals
CAS DataBase Reference: 7664-39-3(CAS DataBase Reference)
NIST Chemistry Reference: Hydrogen fluoride(7664-39-3)
EPA Substance Registry System: Hydrofluoric acid(7664-39-3)
Safety
Hazard Codes : T+,C,T,Xn
Risk Statements : 26/27/28-35-36/37/38-20/21/22
Safety Statements : 26-36/37/39-45-7/9-36/37-28-36
RIDADR : UN 1790 8/PG 2
WGK Germany : 2
RTECS : MW7875000
Hazard Note : Corrosive
HazardClass : 8
PackingGroup : II
Hazardous Substances Data: 7664-39-3(Hazardous Substances Data)

Hydrofluoric acid Chemical Properties,Usage,Production

Chemical Properties
colourless gas with a pungent odour
Air & Water Reactions
Fumes in air. Fumes are highly irritating, corrosive, and poisonous. Generates much heat on dissolution [Merck, 11th ed., 1989]. Heat can cause spattering, fuming, etc.
Reactivity Profile
Hydrofluoric acid attacks glass and any other silica containing material. May react with common metals (iron, steel) to generate flammable hydrogen gas if diluted below 65% with water. Reacts exothermically with chemical bases (examples: amines, amides, inorganic hydroxides). Can initiate polymerization in certain alkenes. Reacts with cyanide salts and compounds to release gaseous hydrogen cyanide. May generate flammable and/or toxic gases with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides. Additional gas-generating reactions may occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), and carbonates. Can catalyze (increase the rate of) chemical reactions. Reacts explosively with cyanogen fluoride, methanesulfonic acid or glycerol mixed with nitric acid. Reacts violently with arsenic trioxide, phosphorus pentachloride, acetic anhydride, alkali metals, ammonium hydroxide, chlorosulfonic acid, ethylenediamine, fluorine, potassium permanganate, oleum, propylene oxide, vinyl acetate, mercury(II) oxide. Emits highly corrosive fumes of hydrogen fluoride gas when heated [Sax, 9th ed., 1996, p. 1839]. Contact with many silicon compounds and metal silicides causes violent evolution of gaseous silicon tetrafluoride [Mellor, 1956, Vol. 2, suppl. 1, p. 121].
Health Hazard
Ingestion of an estimated 1.5 grams produced sudden death without gross pathological damage. Repeated ingestion of small amounts resulted in moderately advanced hardening of the bones. Contact of skin with anhydrous liquid produces severe burns. Inhalation of anhydrous hydrogen fluoride or hydrogen fluoride mist or vapors can cause severe respiratory tract irritation that may be fatal.
Fire Hazard
When heated, Hydrofluoric acid emits highly corrosive fumes of fluorides. Its corrosive action on metals can result in formation of hydrogen in containers and piping to create fire hazard. Toxic and irritating vapors are generated when heated. Will attack glass, concrete, and certain metals, especially those containing silica, such as cast iron. Will attack natural rubber, leather, and many organic materials. May generate flammable hydrogen gas in contact with some metals.
Hydrofluoric acid Preparation Products And Raw materials
Raw materials
SULFURIC ACID Calcium chloride HYDROGEN FLUORIDE GAS Calcium fluoride Microvoid filter film Calcium chloride hexahydrate Sulfuric acid
Preparation Products
Copper(II) borofluoride 6,9-Difluoropregn-4-ene-11,17,21-triol-3,20-dione17,21-diacetate Zinc tetrafluoroborate 9-Fluoropregna-1,4-diene-11,17,21-triol-3,20-dione17,21-diacetate 2-Chloro-6-fluorotoluene TANTALUM(V) OXIDE LANTHANUM FLUORIDE Sevoflurane 3-TRIFLUOROMETHYL BENZOTRICHLORIDE 2,4-Dichlorobenzotrifluoride YTTRIUM FLUORIDE emulsifier acid Boron trifluoride acetonitrile complex 1,1,1,2,3,3,3-Heptafluoropropane 1,3-Bis(trifluoromethyl)-benzene Titanium tetrafluoride 5-(trifluoromethyl)thiazol-2-amine Sodium trifluoromethanesulfonate Lithium fluoride Barium fluoride CHLOROTRIFLUOROMETHANE Potassium fluoroaluminate 1-CHLORO-3-FLUOROISOPROPANOL Strontium fluoride Ethyl 2-methylbutyrate Neodymium trifluoride Lithium hexafluorophosphate 6alpha,9-difluoro-11beta,17,21-trihydroxypregna-1,4-diene-3,20-dione 17,21-di(acetate) 9-fluoro-11beta,21-dihydroxypregna-1,4,16-triene-3,20-dione 21-acetate 1-Chloro-1,1-difluoroethane CHROMIUM(III) FLUORIDE Potassium hexafluoraluminate ZINC TETRAFLUOROBORATE HYDRATE Doxycycline Magnesium fluoride Dichloromonofluoromethane 1,1,1-Trichlorotrifluoroethane Chromium(III) fluoride tetrahydrate 9-Fluoro-11,16,17,21-tetrahydroxypregna-1,4-diene-3,20-dione 21-acetate Potassium heptadecafluoro-1-octanesulfonate
Hydrofluoric acid Suppliers      Global( 206)Suppliers     
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Acide fluorhydrique acidefluorhydrique acidefluorhydrique(french) Acido fluoridrico acidofluorhidrico acidofluoridrico Anhydrous hydrofluoric acid antisal2b caswellno484 epapesticidechemicalcode045601 Fluonrasserstoff fluorhydricacid Fluoric acid Fluorowodor fluorowodor(polish) fluorured’hydrogeneanhydre(french) fluorurodehidrogenoanhidro Fluorwasserstoff Fluorwaterstof hydrofluoric Hydrofluoric acid gas hydrofluoricacid,solution Hydrofluoride Hydrogenfluorid Hydrogenfluoridepolymer Rcra waste number U134 rcrawastenumberu134 Rubigine Synthetic Reagents Trace Analysis Reagents Puriss p.a. ACS Puriss p.a. General Use Inorganic Acids HU - HZ 7664-39-3 Alphabetic Analytical Chromatography Product Catalog Analytical Reagents Analytical Standards FLUOHYDRIC ACID HYDROFLUORIC ACID ANTIDOTE GEL HYDROFLUORIC ACID Hydrogen fluoride,anhydrous Hydrogen fluride HF 70% HYDROFLUORIC ACI Hydrofluoric acid(HF) Hydrogen fluoride/melamine (80% HF) HYDROFLUORIC ACID 49% SEMICONDUCTOR GRAD HYDROFLUORIC ACID 51-55 %, TECHNICAL HYDROFLUORIC ACID 48% A.C.S. REAGENT Hydrofluoric acid 50 % HYDROFLUORIC ACID 51-55 %, TECHN. HYDROFLUORIC ACID 40 %, R. G., REAG. ISO HYDROGEN FLUORIDE CYL. WITH 5 L (NET ~4. 4 KG) HYDROFLUORIC ACID 40% SEMICONDUCTOR GRAD HYDROFLUORIC ACID 47-51%, FOR TRACE ANAL YSIS
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