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Diethylzinc

CAS No.557-20-0
Chemical Name:Diethylzinc
Synonyms:DEZ;DEZn;Et2Zn;CHEMR23;(C2H5)2Zn;ZINC ETHYL;Zinc ethide;ZINCDIETHYL;diethylzine;diethyl-zin
CBNumber:CB7149427
Molecular Formula:C4H10Zn
Formula Weight:123.51
MOL File:557-20-0.mol
Diethylzinc Property
mp : −28 °C(lit.)
bp : 98 °C
density : 1.205 g/mL at 25 °C(lit.)
refractive index : n20/D 1.498(lit.)
Fp : 45 °F
storage temp. : 0-6°C
Water Solubility : REACTS VIOLENTLY
Sensitive : Air & Moisture Sensitive
Merck : 14,3131
CAS DataBase Reference: 557-20-0(CAS DataBase Reference)
NIST Chemistry Reference: Diethylzinc(557-20-0)
EPA Substance Registry System: Zinc, diethyl-(557-20-0)
Safety
Hazard Codes : F,Xn,N,C
Risk Statements : 14-17-34-50/53-67-65-62-48/20-11-51/53-14/15-63
Safety Statements : 26-45-61-62-8-36/37/39-16-60-43
RIDADR : UN 3399 4.3/PG 1
WGK Germany : 2
RTECS : ZH2077777
F : 10-23
TSCA : Yes
HazardClass : 4.3
PackingGroup : I
Hazardous Substances Data: 557-20-0(Hazardous Substances Data)

Diethylzinc Chemical Properties,Usage,Production

Chemical Properties
Clear colorless solution
General Description
Diethylzinc is a pyrophoric liquid with a garlic-like odor. Diethylzinc is stable when Diethylzinc is shipped in sealed tubes with carbon dioxide. Diethylzinc may decompose violently in water and ignite spontaneously with air. Diethylzinc is toxic by ingestion. If exposed to heat or flame, containers of Diethylzinc may explode. Diethylzinc is used as an aircraft fuel.
Air & Water Reactions
Highly flammable. Ignites in air with a blue flame giving off a peculiar garlic-like odor, [Merck, 11th ed., 1989]. Diethyl zinc is spontaneously flammable in air, [Douda(1966)]. Reacts violently with water to form flammable ethane gas, [Brauer(1965)].
Reactivity Profile
Diethylzinc is pyrophoric in air, Diethylzinc ignites instantaneously. Diethylzinc reacts explosively with alcohols (methanol, ethanol), bromine, chlorine or liquefied sulfur dioxide [Houben-Weyl, 1973, 13.2a, p. 855, 757, 709]. Reaction with water, nitro compounds, arsenic trichloride, phosphorus trichloride is violent [Bretherick, 5th ed., 1995, p. 587].
Health Hazard
Inhalation of mist or vapor causes immediate irritation of nose and throat; excessive or prolonged inhalation of fumes from ignition or decomposition may cause ``metal fume fever'' (sore throat, headache, fever, chills, nausea, vomiting, muscular aches, perspiration, constricting sensation in lungs, weakness, sometimes prostration); symptoms usually last 12-24 hrs., with complete recovery in 24-48 hrs. Eyes are immediately and severely irritated on contact with liquid, vapor, or dilute solution; without thorough irrigation, cornea may be permanently damaged. Moisture in skin combines with chemical to cause thermal and acid burns; tissue may be scarred without prompt treatment. Ingestion is unlikely but would cause immediate burns at site of contact; pain, nausea, vomiting, cramps, and diarrhea may follow; if untreated, tissue may become ulcerated.
Diethylzinc Preparation Products And Raw materials
Raw materials
Triethylaluminum Zinc chloride
Preparation Products
zinc amides of oxazolidines
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(C2H5)2Zn diethyl-zin diethylzine Transition Metal Compounds Zn (Zinc) Compounds Classes of Metal Compounds ZINCDIETHYL Zinc ethide ZINC ETHYL Reike and Organozinc Reagents Organometallic Reagents Dialkylzincs DIETHYLZINC 557-20-0 DIETHYLZINC, CYLINDER WITH 100 G DIETHYLZINC SOLUTION, IN TOLUENE (1.1 M) DIETHYLZINC, 15 WT. % (1.1M) SOLUTION IN TOLUENE DIETHYLZINC SOLUTION, ~1 M SOLUTION IN H EXANE DIETHYLZINC, 52.0 WT.% ZN (MINIMUM) DIETHYLZINC, FOR CAMBRIDGE NANOTECH INC DIETHYLZINC, 1.0M SOLUTION IN HEXANES DIETHYLZINC, 1.0M SOLUTION IN HEPTANE Diethylene Zinc DEZn Diethylzinc, 1.5M solution in toluene C4H10Zn Diethylzinc, 1M solution in hexane Diethylzinc,elec.gr.(99.999%-Zn)PURATREM Diethylzinc,min.95% Diethylzinc,min.95%(10wt%inhexane)(Sure/Sealbottle) diethylzinc solution DIETHYLZINC , 10% IN HEXANE ZnC2H52 Diethylzinc, nominally 15% w/w in hexane, packaged under Argon in resealable ChemSealTM bottles Diethylzinc, nominally 15% w/w in hexane Diethylzinc (ca. 1mol/L in Hexane) Classes of Metal Compounds Transition Metal Compounds Zn (Zinc) Compounds DIETHYLZINC, 1M in heptane Diethylzinc, nominally 15% w/w in hexane, packaged under Argon in resealable ChemSeal bottles Benzenepropanoic acid, a,4-dichloro-, methyl ester Hydrocinnamic acid, p,a-dichloro-, methyl ester Methyl 2-chloro-3-(p-chlorophenyl)propionate Methyl 3-(p-chlorophenyl)-2-chloropropionate Diethylzinc, min. 95% Diethylzinc1M solution in hexaneAcroSeal§3 Diethylzinc1.5M solution in tolueneAcroSeal§3 Diethylzinc, nominally 15% w/w in hexane, packaged under Argon in resealable ChemSeal^t bottles Diethylzinc (ca. 15% in Toluene, ca. 1mol/L) Diethylzinc (ca. 17% in Hexane, ca. 1mol/L) Diethylzinc solution,Zincdiethyl DIETHYLZINC, FOR CAMBRIDGE NANOTECH INC. ALD SYSTEM Diethylzinc, 1.5M solution in toluene, AcroSeal Diethylzinc [0.9 M solution in hexane] Diethylzinc, min. 95%, 93-3030, contained in 50 ml Swagelok cylinder for CVD/ALD Diethylzinc, 1M solution in hexane, AcroSeal Ethyl zinc[LL
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