ChemicalBook >>Triphenylmethyl chloride>>alpha-Chlorotriphenylmethane(76-83-5)

alpha-Chlorotriphenylmethane(76-83-5)

alpha-Chlorotriphenylmethane(76-83-5)
Product IdentificationBack to Contents
【Product Name】

alpha-Chlorotriphenylmethane
【Synonyms】

[Chloro-di(phenyl)methyl]benzen
1,1',1''-(Chloromethylidyne)tris[benzene
3-Nitrophenyl isocyanate
m-Nitrophenyl isocyanate
Triphenylmethyl chloride
Trityl chloride
【CAS】

3320-87-4
【CAS】

76-83-5
【Formula】

C19H15Cl
【Formula】

C7H4N2O3
【Molecular Weight】

278.77999999999997
【Molecular Weight】

164.12
【EINECS】

200-986-4
【EINECS】

222-025-8
【RTECS】

PA6450000
【RTECS Class】

Other
【Beilstein/Gmelin】

2094060
【Beilstein/Gmelin】

397363
【Beilstein Reference】

4-05-00-02497
【Beilstein Reference】

4-12-00-01604
【EC Class】

irritant
Physical and Chemical PropertiesBack to Contents
【Appearance】

Slightly yellow solid.
【Appearance】

Yellow solid.
【Solubility in water】

Insoluble
【Melting Point】

109 - 112
【Melting Point】

52
【Boiling Point】

374
【Boiling Point】

120 - 125 (0.7 torr)
【Vapor Pressure】

2E-5 (25 C)
【Density】

1.25 g/cm3
【Partition Coefficient】

5.57
【Heat Of Vaporization】

59.7 kJ/mol
【Heat Of Combustion】

-9833 kJ/mol
【Vapor Density】

9.6
【Refractive Index】

1.5 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Ingestion】

Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration.
【Inhalation】

Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. At high concentrations, isocyanates affect mucous membranes of the respiratory tract and may lead to fatal pulmonary edema. Exposure to low and often even unmeasurable isocyanate concentration results in sensitization. Can produce delayed pulmonary edema.
【Skin】

Causes skin irritation. Organic isocyanates can cause local irritation and allergic reactions.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Causes eye irritation. Lachrymator. May cause chemical conjunctivitis.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Keep container tightly closed. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.
【Handling】

Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
Hazards IdentificationBack to Contents
【Ingestion】

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
【Inhalation】

Causes chemical burns to the respiratory tract.
【Skin】

Causes skin burns.
【Eyes】

Causes eye burns.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 34
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

1759
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Effects may be delayed. Chronic overexposure to isocyanates has been reported to cause lung damage, including decreased lung fuction, which may be permanent.
Fire Fighting MeasuresBack to Contents
【Flash Point】

109
【Flash Point】

178
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Extinguishing media: Use agent most appropriate to extinguish fire. Do NOT get water inside containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.
Stability and ReactivityBack to Contents
【Incompatibilities】

Moisture, strong oxidizing agents, strong acids.
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents.
【Disposal Code】

3
【Decomposition】

Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
【Decomposition】

Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1759
【Hazard Class】

8
【Packing Group】

I; II; III
【HS Code】

2903 69 90
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