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Chlorotrimethylsilane
Chlorotrimethylsilane Suppliers list
Company Name:
Thermo Fisher Scientific
Gold
Tel:
800-810-5118
Email:
cnchemical@thermofisher.com
Products Intro:
Product Name:ChlorotriMethylsilane, 98%
CAS:75-77-4
Purity:98% Package:2.5LT Remarks:ACROS 110120250
Company Name:
Zhengzhou Alfachem Co., Ltd.
Gold
Tel:
0371- 53732842;13383863444 QQ:1065526125
Email:
gekun@alfachem.cn
Products Intro:
Product Name:ChlorotriMethylsilane
CAS:75-77-4
Purity:99% Package:1kg;5kg;10kg;25kg
Company Name:
RiZhao LiDeShi Chemical Co., Ltd.
Gold
Tel:
010-51268198
Email:
leadershipchem@126.com
Products Intro:
CAS:75-77-4
Purity:>=99%
Company Name:
360 Reagent
Gold
Tel:
02566028182 66015035 66026192 66113011 66018217
Email:
sales@360reagent.com/ sales@aikonchem.com
Products Intro:
Product Name:ChlorotriMethylsilane
CAS:75-77-4
Purity:95% Package:1g;5g;10g
Company Name:
Alfa Aesar
Gold
Tel:
400-610-6006; 021-67582000
Email:
saleschina@alfa-asia.com
Products Intro:
Product Name:ChlorotriMethylsilane, 98+%
CAS:75-77-4
Package:25Ml Remarks:A13651
Chlorotrimethylsilane Basic information
Product Name:
Chlorotrimethylsilane
Synonyms:
DOW CORNING(R) PRODUCT Z-1224
;
CHLOROTRIMETHYLSILANE
;
SILANE M3
;
TMCS
;
TMSCL
;
TRIMETHYLSILYL CHLORIDE
;
TRIMETHYL SILICON CHLORIDE
;
TRIMETHYLCHLOROSILANE
CAS:
75-77-4
MF:
C3H9ClSi
MW:
108.64
EINECS:
200-900-5
Product Categories:
Pharmaceutical Intermediates
;
Chloro
;
Organics
;
Analytical Chemistry
;
Biochemistry
;
GC Derivatizing Reagents
;
Monochlorosilanes
;
Nucleosides, Nucleotides & Related Reagents
;
Protecting Agents for Hydroxyl and Amino Groups
;
Protecting Agents, Phosphorylating Agents & Condensing Agents
;
Protection & Derivatization Reagents (for Synthesis)
;
Reagents for Oligosaccharide Synthesis
;
Si (Classes of Silicon Compounds)
;
Si-Cl Compounds
;
Silicon Compounds (for Synthesis)
;
Silylation (GC Derivatizing Reagents)
;
Synthetic Organic Chemistry
;
Trimethylsilylation (GC Derivatizing Reagents)
;
Blocking Agents
;
Chloro Silanes
;
Protective Agents
;
Silylating Agents
;
organosilicon compounds
;
Silylation Reagents
Mol File:
75-77-4.mol
Chlorotrimethylsilane Chemical Properties
mp
−40 °C(lit.)
bp
57 °C(lit.)
density
1.257 g/mL at 25 °C
vapor density
3.7 (vs air)
vapor pressure
100 mm Hg ( 25 °C)
refractive index
n
20/D
1.500
Fp
104 °F
storage temp.
Store at RT.
Water Solubility
REACTS
Sensitive
Moisture Sensitive
BRN
1209232
Stability:
Stable. Highly flammable - note low flash point. Reacts violently with water. Incompatible with water, moisture, strong oxidizing agents, strong acids, strong bases, aldehydes, alcohols, amines, esters, ketones.
CAS DataBase Reference
75-77-4(CAS DataBase Reference)
NIST Chemistry Reference
Silane, chlorotrimethyl-(75-77-4)
EPA Substance Registry System
Silane, chlorotrimethyl-(75-77-4)
Safety Information
Hazard Codes
T,F,C,Xn
Risk Statements
20/21-36/38-34-21-14-11-37-35-19-40-10-67-20/21/22-52
Safety Statements
26-36/37/39-45-16-36/37-7/9
RIDADR
UN 2924 3/PG 2
WGK Germany
2
RTECS
VV2710000
F
10-21
Hazard Note
Highly Flammable/Corrosive/Moisture Sensitive
TSCA
Yes
HazardClass
3
PackingGroup
II
HS Code
29310095
Hazardous Substances Data
75-77-4(Hazardous Substances Data)
MSDS Information
Provider
Language
Chlorotrimethylsilane
English
ACROS
English
SigmaAldrich
English
ALFA
English
Chlorotrimethylsilane Usage And Synthesis
Chemical Properties
Colorless liquid
Usage
Chlorotrimethylsilane have been used in the preparation of volatile derivatives of a wide range of compounds for GC analysis. Chlorotrimethylsilane has been used for silylation and as a protection gro up in the process of various organic synthesis.
General Description
A colorless fuming liquid with a pungent odor. Boiling point 135°F Flash point -18°F. Density 0.854 g / cm3. The vapor and liquid may cause burns. Vapors are heavier than air.
Reactivity Profile
Chlorotrimethylsilane reacts vigorously and exothermically with water to produce hydrogen chloride.
Health Hazard
Similar to other silanes. Toxicity is rated high for inhalation, ingestion and local irritation. May cause death or permanent injury after a very short exposure to small quantities.
Fire Hazard
Violent reaction with water. Toxic and irritating hydrogen chloride and phosgene may be formed in fires. Difficult to extinguish, re-ignition may occur. Flashback along vapor trail may occur. Containers may explode in fire. Vapor may explode if ignited in enclosed area. When heated to decomposition or on contact with acids or acid fumes, chloride fumes are emitted. Reacts with surface moisture, releasing hydrogen chloride, which will corrode common metals and form flammable hydrogen gas. Avoid contact with water; Chlorotrimethylsilane readily hydrolyzes, liberating hydrochloric acid. Hazardous polymerization may not occur.
Chlorotrimethylsilane Preparation Products And Raw materials
Preparation Products
(2R)-2-[(4-Ethyl-2,3-dioxopiperazinyl)carbonylamino]-2-phenylacetic acid
-->
5-FLUORO-2-PICOLINIC ACID
-->
(Trifluoromethyl)trimethylsilane
-->
Hexamethyldisilazane
-->
Thiophene-2-ethylamine
-->
Rhodanine-3-acetic acid
-->
Pyridine sulfur trioxide
-->
6-IODO-PYRIDINE-2-CARBOXYLIC ACID
-->
Cefoperazone
-->
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
-->
Trimethylsilylacetylene
-->
(2R)-2-[(4-Ethyl-2,3-dioxopiperazinyl)carbonylamino]-2-(4-hydroxyphenyl)acetic acid
-->
4-AMINO-2,6-DIFLUORO-BENZALDEHYDE
-->
Hexamethyldisiloxane
-->
2,4-DIMETHOXYPHENETHYLAMINE
-->
5-BROMO-3-FLUORO-2-PYRIDINONE
-->
5-BROMO-3-CHLORO-2-PYRIDINONE
-->
Aniracetam
-->
TRIS(TRIMETHYLSILYL)SILANE
-->
Thiazole-4-carboxaldehyde
-->
6-CYANONICOTINIC ACID
-->
ROKITAMYCIN
-->
2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
-->
7-Aminocephalosporanic acid
-->
Bis(trimethylsilyl)acetylene
-->
2,4-DIMETHYLQUINOLINE-3-CARBOXYLIC ACID
-->
Azidotrimethylsilane
-->
4'-Iodoacetophenone
-->
Ethoxytrimethylsilane
-->
2-ETHYL-4-METHYLQUINOLINE-3-CARBOXYLIC ACID
-->
BIS(TRIMETHYLSILYL)PEROXIDE
-->
ETHYL 2,4-DIMETHYLQUINOLINE-3-CARBOXYLATE
-->
ETHYL 2-(CHLOROMETHYL)-4-PHENYLQUINOLINE-3-CARBOXYLATE
-->
ETHYL 2-(CHLOROMETHYL)-4-PHENYLQUINOLINE-3-CARBOXYLATE HYDROCHLORIDE
-->
Tegafur
-->
1-(2,4-DIMETHYLQUINOLIN-3-YL)ETHANONE HYDROCHLORIDE
-->
ETHYL 2-(CHLOROMETHYL)-4-METHYLQUINOLINE-3-CARBOXYLATE HYDROCHLORIDE
-->
METHYL 2-(CHLOROMETHYL)-4-METHYLQUINOLINE-3-CARBOXYLATE HYDROCHLORIDE
-->
N,O-Bis(trimethylsilyl)acetamide
-->
Allyltrimethylsilane
Raw materials
Acetyl chloride
-->
Cuprous chloride
-->
METHYL CHLORIDE
-->
Silicon
-->
Chloromethyl silane
-->
Tetramethylsilane
Tag:
Chlorotrimethylsilane(75-77-4)
Related Product Information
Dimethyldimethoxysilane
Hexamethyldisilane
Trifluoroacetic acid
Triethylamine
(Trifluoromethyl)trimethylsilane
Choline chloride
Polyvinyl chloride
Potassium chloride
Bromotrimethylsilane
Chloromethyl silane
DIMETHYLTHEXYLSILYL CHLORIDE
Sodium chloride
Benzyl chloride
TRIMETHYLSILANE
CHLOROPHENYLSILANE 97
CHLORIDE STANDARD
Calcium chloride
Iodotrimethylsilane
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