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CAS番号. | 62-53-3 |
化学名: | アニリン |
别名: | アニリン;ベンゼン-1-アミン;4-アミノベンゼン;アミノベンゼン;3-アミノベンゼン;1-アミノベンゼン;フェニルアミン;ベンゼンアミン;キアノール;アミノフェン |
英語化学名: | Aniline |
英語别名: | Anilin;Anyvim;Kyanol;Anilina;blueoil;ci76000;ANILINE;Benzidam;Blue Oil;ai3-03053 |
CBNumber: | CB7169544 |
分子式: | C6H7N |
分子量: | 93.13 |
MOL File: | 62-53-3.mol |
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アニリン 物理性質 |
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比重(密度) : |
1.022 g/mL at 25 °C(lit.)
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蒸気密度: |
3.22 (185 °C, vs air)
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安定性:: |
Stable. Incompatible with oxidizing agents, bases, acids, iron and iron salts, zinc, aluminium. Light sensitive. Combustible. |
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アニリン 化学特性,用途語,生産方法 |
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一般的な説明
A yellowish to brownish oily liquid with a musty fishy odor. Melting point -6°C; boiling point 184°C; flash point 158°F. Denser than water (8.5 lb / gal) and slightly soluble in water. Vapors heavier than air. Toxic by skin absorption and inhalation. Produces toxic oxides of nitrogen during combustion. Used to manufacture other chemicals, especially dyes, photographic chemicals, agricultural chemicals and others. |
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空気と水の反応
Darkens on exposure to air and light. Polymerizes slowly to a resinous mass on exposure to air and light. Slightly soluble in water. |
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反応プロフィール
Aniline is a heat sensitive base. Combines with acids to form salts. Dissolves alkali metals or alkaline earth metals with evolution of hydrogen. Incompatible with albumin, solutions of iron, zinc and aluminum, and acids. Couples readily with phenols and aromatic amines. Easily acylated and alkylated. Corrosive to copper and copper alloys. Can react vigorously with oxidizing materials (including perchloric acid, fuming nitric acid, sodium peroxide and ozone). Reacts violently with BCl3. Mixtures with toluene diisocyanate may ignite. Undergoes explosive reactions with benzenediazonium-2-carboxylate, dibenzoyl peroxide, fluorine nitrate, nitrosyl perchlorate, peroxodisulfuric acid and tetranitromethane. Violent reactions may occur with peroxyformic acid, diisopropyl peroxydicarbonate, fluorine, trichloronitromethane (293° F), acetic anhydride, chlorosulfonic acid, hexachloromelamine, (HNO3 + N2O4 + H2SO4), (nitrobenzene + glycerin), oleum, (HCHO + HClO4), perchromates, K2O2, beta-propiolactone, AgClO4, Na2O2, H2SO4, trichloromelamine, acids, FO3Cl, diisopropyl peroxy-dicarbonate, n-haloimides and trichloronitromethane. Ignites on contact with sodium peroxide + water. Forms heat or shock sensitive explosive mixtures with anilinium chloride (detonates at 464° F/7.6 bar), nitromethane, hydrogen peroxide, 1-chloro-2,3-epoxypropane and peroxomonosulfuric acid. Reacts with perchloryl fluoride form explosive products. . |
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健康ハザード
Aniline is classified as very toxic. Probable oral lethal dose in humans is 50-500 mg/kg for a 150 lb. person. Aniline poisoning is characterized by methemoglobin formation in the blood and resulting cyanosis or blue skin. The formation of methemoglobin interferes with the oxygen-carrying capacity of the blood. The approximate minimum lethal dose for a 150 lb. human is 10 grams. Serious poisoning may result from ingestion of 0.25 mL. People at special risk include individuals with glucose-6-phosphate-dehydrogenase deficiency and those with liver and kidney disorders, blood diseases, or a history of alcoholism. |
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火災危険
Combustion can produce toxic fumes including nitrogen oxides and carbon monoxide. Aniline vapor forms explosive mixtures with air. Aniline is incompatible with strong oxidizers and strong acids and a number of other materials. Avoid heating. Hazardous polymerization may occur. Polymerizes to a resinous mass. |
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アニリン 上流と下流の製品情報 |
原材料
窒素
オキソ鉄(II)
ベンゼン [アミノ酸配列分析用]
水素
硝酸 (67%) [一般有機合成用]
ニトロベンゼン
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準備製品
2-アニリノエタノール
2-[2-ヒドロキシ-3-[[(2,3-ジヒドロ-2-オキソ-1H-ベンゾイミダゾール)-5-イル]カルバモイル]-1-ナフチルアゾ]安息香酸ブチル
ベンゼンアミン·塩酸塩
1,3-ジフェニル尿素
2,4,6-トリクロロアニリン
2-[2-ヒドロキシ-3-[[(2,3-ジヒドロ-2-オキソ-1H-ベンゾイミダゾール)-5-イル]カルバモイル]-1-ナフチルアゾ]安息香酸メチル
ポリ(2,2,4トリメチル1,2ジヒドロキノリン)
N-(2,6-ジメチルフェニル)-N'-[イミノ(メチルアミノ)メチル]尿素
N-フェニル-1-ナフチルアミン
2-クロロマロンアルデヒド
3-ヒドロキシジフェニルアミン
6-ヒドロキシ-5-[[4-[[4-(フェニルアミノ)-3-スルホフェニル]アゾ]-1-ナフチル]アゾ]-2-ナフタレンスルホン酸二ナトリウム
p-デシルアニリン
3,3'-(フェニルイミノ)ビスプロパンニトリル
7,7'-(カルボニルジイミノ)ビス[4-ヒドロキシ-3-(フェニルアゾ)-2-ナフタレンスルホン酸]二ナトリウム
C.I.リアクティブブルー50
ソルベントブラック5
3-ブロモ-2-ピリジンカルボン酸 臭化物
ジシクロヘキシルアミン
2-(トリフルオロメチル)-4-キノリノール
N,N'-ジフェニル-1,4-フェニレンジアミン
N-フェニル-2-ナフチルアミン
8-アニリノ-1-ナフタレンスルホン酸
フェニルヒドラジン硫酸塩
2,2'-(1,2-エテンジイル)ビス[5-[[4-[ビス(2-ヒドロキシエチル)アミノ]-6-フェニルアミノ-1,3,5-トリアジン-2-イル]アミノ]ベンゼンスルホン酸]
スダン I
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アニリン 生産企業 Global( 204)Suppliers |
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